RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2

Base Information

• Chemical Name: RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2
• CAS No.: 155229-88-2
• Molecular Formula: C₅₄H₈₆P₂RuSi
• Molecular Weight: 926.38
• Mol file: 155229-88-2.mol

Synonyms:RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2

Chemical Property of RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2

There total 2 articles about RuH₂(H₂)(HSi(C₆H₅)3)(P(C₆H₁₁)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

RuH2(H2)2(tricyclohexylphosphine)2 (112320-11-3) + HSiPh3 (789-25-3) → RuH2(H2)(HSi(C6H5)3)(P(C6H11)3)2 (155229-88-2)

Guidance literature:

In pentane; instantaneous precipitation of the product;; elem. anal.;;

Reference yield:

RuH2(H2)2(tricyclohexylphosphine)2 (112320-11-3) + methylphenylsilane (766-08-5,146088-00-8) → RuH2(H2)(HSi(C6H5)3)(P(C6H11)3)2 (155229-88-2) + (P(C6H11)3)2H2Ru(SiH4)RuH2(P(C6H11)3)2

Guidance literature:

In benzene-d6; byproducts: HSi(C6H5)(CH3)2, HSi(C6H5)2CH3, H(CH3)2SiSi(CH3)2H; addn. in an NMR tube; not isolated, detected by NMR;

DOI:10.1021/ja000223p

Reference yield:

RuH2(H2)(HSi(C6H5)3)(P(C6H11)3)2 (155229-88-2) + nitrogen (7727-37-9) → RuH2(N2)2(P(C6H11)3)2 + HSiPh3 (789-25-3)

Guidance literature:

room temperature;; (1)H-NMR-spectrum;

upstream raw materials:

RuH₂(H₂)2(tricyclohexylphosphine)2

HSiPh₃

methylphenylsilane

Downstream raw materials:

HSiPh₃

RuH₂(H₂)2(tricyclohexylphosphine)2