4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER

Base Information

Chemical Name:4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER
CAS No.:91748-18-4
Molecular Formula:C₁₅H₁₁F₃O₂
Molecular Weight:280.246
Hs Code.:2916399090
Mol file:91748-18-4.mol

Synonyms:Methyl4'-(trifluoromethyl)[1,1'-biphenyl]-2-carboxylate

Suppliers and Price of 4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate 95+%
1g
$ 420.00

CHESS?
SG000208:4'-Trifluoromethyl-biphenyl-2-carboxylicacidmethylester 98
5 g
$ 600.00

American Custom Chemicals Corporation
METHYL-4'-(TRIFLUOROMETHYL)-2-BIPHENYLCARBOXYLATE 98.00%
10G
$ 1940.40

Alichem
Methyl4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate
10g
$ 489.60

Alichem
Methyl4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate
5g
$ 294.00

Activate Scientific
Methyl4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate 95%
5 g
$ 1506.00

Total 7 raw suppliers

Chemical Property of 4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER

Chemical Property:

PSA：26.30000
LogP:4.15900

Purity/Quality:

97% ^*data from raw suppliers

Methyl4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER

There total 7 articles about 4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBOXYLIC ACID METHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 610-97-9
o-iodo-methyl-benzoic acid

: 128796-39-4
4-trifluoromethylphenylboronic acid

: 91748-18-4
methyl 4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: With bis(triphenylphosphine)palladium(II) dichloride; sodium carbonate; In tetrahydrofuran; water; at 80 ℃; for 14h; Schlenk technique; Inert atmosphere; Sealed tube;
DOI:10.1021/acs.orglett.8b00052

Reference yield: 81.0%

: 610-94-6
2-bromobenzoic acid methyl ester

: 128796-39-4
4-trifluoromethylphenylboronic acid

: 91748-18-4
methyl 4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; sodium carbonate; In water; acetonitrile; Reflux;
DOI:10.1039/c5ob01637a

Reference yield: 71.0%

: 610-96-8
methyl chlorobenzoate

: 98-56-6
4-chlorobenzotrifluoride

: 581-80-6
4,4'-bis(trifluoromethyl)biphenyl

: 91748-18-4
methyl 4'-(trifluoromethyl)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: With manganese; cobalt (II) bromide; triphenylphosphine; trifluoroacetic acid; In pyridine; N,N-dimethyl-formamide; at 50 ℃;
DOI:10.1002/anie.200704402