isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose

Base Information

• Chemical Name: isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose
• CAS No.: 194347-81-4
• Molecular Formula: C₂₃H₂₈O₅
• Molecular Weight: 384.472
• Mol file: 194347-81-4.mol

Synonyms:isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose

Chemical Property of isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose

Chemical Property:

Purity/Quality:

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Technology Process of isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose

There total 1 articles about isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

isopropyl alcohol (67-63-0,8013-70-5) + 3,4-di-O-benzyl-6-deoxy-α-L-arabino-hexopyranos-2-ulosyl bromide (194347-72-3) → isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose (194347-81-4)

Guidance literature:

With 4 A molecular sieve; silver carbonate; In dichloromethane; at 20 ℃; for 0.333333h;

DOI:10.1002/ejoc.200300149

Reference yield:

isopropyl 3,4-di-O-benzyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose (194347-81-4) → isopropyl 3,4-di-O-benzyl-β-L-rhamnopyranoside + (2S,3S,4S,5S,6S)-4,5-Bis-benzyloxy-2-isopropoxy-6-methyl-tetrahydro-pyran-3-ol

Guidance literature:

With sodium tetrahydroborate;

DOI:10.1002/ejoc.200300149

upstream raw materials:

isopropyl alcohol

3,4-di-O-benzyl-6-deoxy-α-L-arabino-hexopyranos-2-ulosyl bromide