[(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

Base Information

Chemical Name:[(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)
CAS No.:139684-90-5
Molecular Formula:C₃₇H₄₃I₂NO₄P₂Pd
Molecular Weight:987.929
Hs Code.:

Synonyms:[(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

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Chemical Property of [(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

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Technology Process of [(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

There total 1 articles about [(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 139609-63-5
{PS,3R,4R,P'S}-1-(t-butoxycarbonyl)-3,4-bis-((2-methoxybenzyl)phenylphosphanyl)pyrrolidine

: 139609-64-6
{PR,3R,4R,P'S}-1-(t-butoxycarbonyl)-3,4-bis-((2-methoxybenzyl)phenylphosphanyl)pyrrolidine

: 7790-38-7
palladium(II) iodide

: 139609-69-1
({PR,3R,4R,P'R}-1-(tert-butoxycarbonyl)-3,4-bis{(2-methoxybenzyl)phenylphosphanyl}pyrrolidine-P,P')diiodopalladium

: 139684-90-5
[(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

Guidance literature:: In dichloromethane; Ar atmosphere; dissoln. of org. compd. in CH2Cl2, addn. of solid PdI2, stirring (12 h, exclusion of light); filtration (silica gel), chromy. (silica gel, CH2Cl2, acetic acid ester), evapn., dissoln. (CH2Cl2), evapn., addn. of toluene, ultrasonication, addn. of t-butylmethyl ether, filtration, washing (t-butylmethyl ether), drying (vac.); elem. anal.;

Reference yield: 100.0%

: 139684-90-5
[(PR,3R,4R,P'S)-N-tert-butoxycarbonyl-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

: [(PR,3R,4R,P'S)-3,4-bis(2-methoxybenzyl(phenyl)phosphanyl)pyrrolidine-P,P']diiodopalladium(II)

Guidance literature:: With aq. HCl; Na₂CO₃; In dichloromethane; water; (argon); deprotection with aq. HCl in CH2Cl2 at 0°C for 4 d, thenaddn. of Na2CO3;
DOI:10.1002/cber.19961290712