(C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3)

Base Information

• Chemical Name: (C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3)
• CAS No.: 91742-34-6
• Molecular Formula: C₂₉H₅₀OTh
• Molecular Weight: 646.753
• Mol file: 91742-34-6.mol

Synonyms:(C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3)

Chemical Property of (C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3)

There total 1 articles about (C₅(CH₃)5)2Th(CH₂C(CH₃)3)(OC(CH₃)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

bis(pentamethylcyclopentadienyl)thorium(IV) t-butoxide chloride + neopentyl lithium (7412-67-1) → (C5(CH3)5)2Th(CH2C(CH3)3)(OC(CH3)3) (91742-34-6)

Guidance literature:

In n-heptane; byproducts: LiCl; heptane was condensed at -78°C onto a mixt. of Th-complex and t-BuCH2Li under vac., the reaction vessel placed under 1 atm of Ar, after 10 min the suspn. was allowed to warm to room temp. and stirred for 2 h; filtered, ppt. was washed 2 times by condensing portions of heptane from the filtrate into the upper part of the filtration apparatus, combined washings and filtrate were concd., cooled (-78°C), crystals were filtered, dried in vacuo; elem. anal.;

DOI:10.1021/ja00335a031

upstream raw materials:

neopentyl lithium