1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene

Base Information

• Chemical Name: 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene
• CAS No.: 78822-68-1
• Molecular Formula: C₂₀H₃₂O
• Molecular Weight: 288.473
• Mol file: 78822-68-1.mol

Synonyms:1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene

Chemical Property of 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene

There total 2 articles about 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-4-methoxy-benzene (104-92-7) + (E)-β-ionone (79-77-6,14901-07-6) → 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene (78822-68-1)

Guidance literature:

Yield given. Multistep reaction;

Reference yield:

1-bromo-4-methoxy-benzene (104-92-7) + (E)-β-ionone (79-77-6,14901-07-6) → 1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene (78822-68-1) + 1-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-3-(p-methoxyphenyl)butane (78822-70-5)

Guidance literature:

With ethanol; potassium chloride; ammonia; lithium; magnesium chloride; Yield given. Multistep reaction; 1.) THF, -60 deg C, 20 min.; to room temp., 45 min.; 2.) 3h;

DOI:10.1021/jo00334a006

Reference yield:

1-methoxy-4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-propyl>-1,4-cyclohexadiene (78822-68-1) → 4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)propyl>-3-cyclohexen-1-one (129194-23-6)

Guidance literature:

With sulfuric acid; In tetrahydrofuran; for 2h; Yield given; Heating;

upstream raw materials:

1-bromo-4-methoxy-benzene

(E)-β-ionone

Downstream raw materials:

4-<1-methyl-3-(2,6,6-trimethyl-1-cyclohexen-1-yl)propyl>-3-cyclohexen-1-one