((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4]

Base Information

• Chemical Name: ((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4]
• CAS No.: 476153-00-1
• Molecular Formula: C₁₅H₃₇OP₂Pt*C₃₂H₁₂BF₂₄
• Molecular Weight: 1353.71
• Mol file: 476153-00-1.mol

Synonyms:((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4]

Chemical Property of ((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of ((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4]

There total 1 articles about ((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=[((C₂H₅)2PCH₂)2Pt(CH₃)(O(C₂H₅)2)][B(C₆H₃(CF₃)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex + (1,2-bis(diethylphosphino)ethane)PtMe2 (121922-97-2) → ((C2H5)2PCH2)2Pt(CH3)(O(C2H5)2)(1+)*B(C6H3(CF3)2)4(1-)=[((C2H5)2PCH2)2Pt(CH3)(O(C2H5)2)][B(C6H3(CF3)2)4] (476153-00-1)

Guidance literature:

In diethyl ether; byproducts: CH4; under He atm. using Schlenk techniques; to stirred soln. of (H(OEt2)2B(C6H3(CF3)2)4 in Et2O at room temp. added Pt-complex as solid; vol. reduced; hexane added; placed in a freezer at -30°C for 1 d;filtrate decanted off; washed (hexane); dried (vac.);

DOI:10.1021/ja020798h

Reference yield: 98.0%

((C2H5)2PCH2)2Pt(CH3)(O(C2H5)2)(1+)*B(C6H3(CF3)2)4(1-)=[((C2H5)2PCH2)2Pt(CH3)(O(C2H5)2)][B(C6H3(CF3)2)4] (476153-00-1) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [[((C2H5)2PCH2)2Pt]2(μ-biphenyl)][B(C6H3(CF3)2)4]2

Guidance literature:

In benzene; byproducts: CH4; under He atm. using Schlenk techniques; Pt complex suspended in benzene and heated to 80°C for 5 min (alternatively at 25°C for 4 h); soln. cooled to room temp.; solvent decanted off; oil washed (benzene); dried (vac.); dissolved (CH2Cl2); layered (hexane); crystals were obtained; elem. anal.;

DOI:10.1021/ja020798h

upstream raw materials:

(1,2-bis(diethylphosphino)ethane)PtMe₂