(2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Base Information

Chemical Name:(2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane
CAS No.:1448042-64-5
Molecular Formula:C₅₉H₆₈Cl₂O₁₀Si₂
Molecular Weight:1064.26
Hs Code.:

Synonyms:(2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Suppliers and Price of (2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

There total 2 articles about (2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 1096143-75-7
1,3-di-O-tert-butyldiphenylsilylglycerol

: 1400562-33-5
phenyl 2,3-di-O-benzyl-4,6-di-O-chloroacetyl-1-thio-β-D-galactopyranoside

: 1448042-64-5
(2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; for 0.0833333h; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1016/j.tet.2013.06.038

Reference yield:

: 231623-55-5
phenyl 2,3-di-O-benzyl-1-thio-β-D-galactopyranoside

: 1448042-64-5
(2R)-1,3-di-O-tert-butyldiphenylsilyl-2-O-(4,6-di-O-chloroacetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-1,2,3-trihydroxypropane

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 0 °C / Inert atmosphere

2: N-iodo-succinimide; trifluorormethanesulfonic acid / dichloromethane / 0.08 h / 0 °C / Molecular sieve; Inert atmosphere

With pyridine; N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane;
DOI:10.1016/j.tet.2013.06.038