1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene

Base Information

• Chemical Name: 1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene
• CAS No.: 106032-02-4
• Molecular Formula: C₂₁H₁₆S
• Molecular Weight: 300.424
• Mol file: 106032-02-4.mol

Synonyms:1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene

Chemical Property of 1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene

There total 1 articles about 1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

(1α,1aβ,9bβ)-1-chloro-1a,9b-dihydrocyclopropaphenanthrene (55831-21-5) + thiophenol (108-98-5) → 1a,9b-dihydro-1a-(phenylthio)-1H-cyclopropaphenanthrene + 1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene (106032-02-4)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; In tetrahydrofuran; dimethyl sulfoxide; 4 deg C, 20 h, RT, 4 d;

DOI:10.1002/hlca.19860690412

Reference yield: 88.0%

1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene (106032-02-4) → 1a,9b-dihydro-1-'exo'-(phenylsulfonyl)-1H-cyclopropaphenanthrene

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; for 25h; Ambient temperature;

DOI:10.1002/hlca.19860690412

Reference yield: 81.0%

1a,9b-dihydro-1-'exo'-phenylthio-1H-cyclopropaphenanthrene (106032-02-4) → 1a,9b-dihydro-1-'exo'-(phenylsulfinyl)-1H-cyclopropaphenanthrene + 1a,9b-dihydro-1-'exo'-(phenylsulfonyl)-1H-cyclopropaphenanthrene

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; for 21h; Ambient temperature;

DOI:10.1002/hlca.19860690412

upstream raw materials:

(1α,1aβ,9bβ)-1-chloro-1a,9b-dihydrocyclopropaphenanthrene

thiophenol