(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

Base Information

Chemical Name:(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether
CAS No.:162466-13-9
Molecular Formula:C₂₇H₃₂O₄Si
Molecular Weight:448.634
Hs Code.:

Synonyms:(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

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Chemical Property of (2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

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Technology Process of (2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

There total 3 articles about (2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 162466-12-8
(2S,3R)-3-acetoxyl-3-phenyl-1,2-propanediol

: 162466-13-9
(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

Guidance literature:: With 1H-imidazole; In tetrahydrofuran; for 24h; Ambient temperature;
DOI:10.1016/0040-4020(94)01025-U

Reference yield:

: 4407-36-7
(2E)-3-phenyl-2-propen-1-ol

: 162466-13-9
(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / 4 Angstroem mol. sieves, (L)+diisopropyl tartarate, Ti(i-PrO)4, t-BuOOH / CH₂Cl₂ / 1 h / -15 - -5 °C

2: 90 percent / CHCl₃ / 3 h / -20 - 0 °C

3: 94 percent / imidazole / tetrahydrofuran / 24 h / Ambient temperature

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; 4 A molecular sieve; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1016/0040-4020(94)01025-U

Reference yield:

: 21915-53-7,40641-81-4,98819-67-1,98819-68-2,99528-63-9,104196-23-8,105663-44-3,116661-35-9,91465-28-0
(2R,3S)-(3-phenyloxiran-2-yl)methanol

: 162466-13-9
(2S,3R)-2-hydroxy-3-acetoxyl-3-phenylpropanyl tert-butyldiphenylsilyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / CHCl₃ / 3 h / -20 - 0 °C

2: 94 percent / imidazole / tetrahydrofuran / 24 h / Ambient temperature

With 1H-imidazole; In tetrahydrofuran; chloroform;
DOI:10.1016/0040-4020(94)01025-U