cyclobutylmethyl phenyl selenide

Base Information

• Chemical Name: cyclobutylmethyl phenyl selenide
• CAS No.: 1404380-69-3
• Molecular Formula: C₁₁H₁₄Se
• Molecular Weight: 225.192
• Mol file: 1404380-69-3.mol

Synonyms:cyclobutylmethyl phenyl selenide

Chemical Property of cyclobutylmethyl phenyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclobutylmethyl phenyl selenide

There total 2 articles about cyclobutylmethyl phenyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

diphenyl diselenide (1666-13-3) + cyclobutylmethyl iodide (16408-62-1) → cyclobutylmethyl phenyl selenide (1404380-69-3)

Guidance literature:

With zinc; In acetonitrile; for 0.0833333h; pH=14;

DOI:10.1016/j.tetlet.2012.09.063

Reference yield:

(Bromomethyl)cyclobutane (17247-58-4) + diphenyl diselenide (1666-13-3) → cyclobutylmethyl phenyl selenide (1404380-69-3)

Guidance literature:

diphenyl diselenide; With sodium tetrahydroborate; In ethanol; at 20 ℃; for 0.5h; Inert atmosphere;

(Bromomethyl)cyclobutane; In ethanol; at 20 ℃; for 20h; Inert atmosphere;

DOI:10.1021/acs.orglett.9b03375

Reference yield:

cyclobutylmethyl phenyl selenide (1404380-69-3) → cyclobutylmethyl phenyl selenone

Guidance literature:

With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; at 20 ℃; for 6h;

DOI:10.1021/acs.orglett.9b03375

upstream raw materials:

diphenyl diselenide

cyclobutylmethyl iodide

(Bromomethyl)cyclobutane

Refernces

• 1、 Dos Anjos, Jose Ayron Lira,Bieber, Lothar Wilhelm. "Radical intermediates in the Zn-promoted Barbier-type alkylation of diphenyl diselenide in aqueous medium". . p. 6492 - 6494,3. Retrieved 2012/12/12.