2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane

Base Information

Chemical Name:2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane
CAS No.:95245-29-7
Molecular Formula:C₂₁H₃₃NO₁₀
Molecular Weight:459.494
Hs Code.:
Mol file:95245-29-7.mol

Synonyms:4,7-Epoxy-1,3-dioxolo[4,5-c]oxepin,b-D-mannopyranose deriv.

Suppliers and Price of 2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1,3-Bis-(1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propylamine
25mg
$ 300.00

Biosynth Carbosynth
2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane
10 mg
$ 173.30

Biosynth Carbosynth
2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane
5 mg
$ 89.30

Biosynth Carbosynth
2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane
25 mg
$ 315.00

American Custom Chemicals Corporation
2-AMINO-1,3-BIS(1,6-ANHYDRO-2,3-O-ISOPROPYLIDENE-B-D-MANNOPYRANOSE-4-O-YL)-PROPANE 95.00%
10MG
$ 329.70

Total 6 raw suppliers

Chemical Property of 2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane

Chemical Property:

Melting Point:131-134°C
PSA：118.32000
LogP:0.33480
Storage Temp.:-20°C Freezer
Solubility.:Chloroform, Ethyl Acetate

Purity/Quality:

95% ^*data from raw suppliers

1,3-Bis-(1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propylamine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses 2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane is used in the synthesis of novel bis(D-mannose) compounds.

Technology Process of 2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane

There total 4 articles about 2-Amino-1,3-bis(1,6-anhydro-2,3-O-isopropylidene-b-D-mannopyranose-4-O-yl)-propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1,3-Bis-((1R,2S,6S,7R,8R)-4,4-dimethyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.0^2,6]undec-7-yloxy)-propan-2-one O-benzyl-oxime

: 95245-29-7
1,3-bis(1,6-anydro-4-deoxy-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propylamine

Guidance literature:: With ammonium hydroxide; hydrogen; nickel; In methanol; for 48h; Ambient temperature;
DOI:10.1002/(SICI)1099-1344(199701)39:1<21::AID-JLCR937>3.0.CO;2-2

Reference yield: 70.0%

: 95245-28-6
1,3-bis(1,6-anydro-4-deoxy-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propanone

: 95245-29-7
1,3-bis(1,6-anydro-4-deoxy-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propylamine

Guidance literature:: With ammonium acetate; sodium cyanoborohydride; In tetrahydrofuran; methanol; at 25 ℃; for 48h;
DOI:10.1016/S0008-6215(00)90786-9

Reference yield:

: 14440-51-8
1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose

: 95245-29-7
1,3-bis(1,6-anydro-4-deoxy-2,3-O-isopropylidene-β-D-mannopyranose-4-yloxy)-2-propylamine

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) DMF, RT, 2.) DMF, a.) RT, overnight, b.) 45 deg C, 4 h

2: 75 percent / aq. NH₃, H₂ / 50percent Raney nickel / methanol / 48 h / Ambient temperature

With ammonium hydroxide; hydrogen; sodium hydride; nickel; In methanol;
DOI:10.1002/(SICI)1099-1344(199701)39:1<21::AID-JLCR937>3.0.CO;2-2