2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

Base Information

Chemical Name:2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde
CAS No.:253446-47-8
Molecular Formula:C₁₂H₂₀O₂
Molecular Weight:196.29
Hs Code.:

Synonyms:2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

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Chemical Property of 2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

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Technology Process of 2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

There total 9 articles about 2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 253446-46-7
2-methoxymethyl-N-methoxy-N-methyl-6,6-dimethyl-2-cyclohexene-1-acetamide

: 253446-47-8
2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

: 2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-ethanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at -78 ℃; for 48h;
DOI:10.1016/S0040-4020(99)00764-4

Reference yield:

: 4255-62-3
4,4-dimethylcyclohexane-1-one

: 253446-47-8
2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

Guidance literature:: Multi-step reaction with 9 steps

1: 33 percent

2: 63 percent / CH₂Cl₂ / 240 h / 20 °C

3: 110 mg / L-selectride / tetrahydrofuran / 20 °C

4: 3.189 g / silica gel / diethyl ether; ethyl acetate; petroleum ether

5: 86 percent / NaBH(OAc)3 / acetic acid / 12 h / 20 °C

6: 96 percent / Me₃Al / hexane; CH₂Cl₂ / 0.5 h / 0 °C

7: 87 percent / imidazole / tetrahydrofuran / 14 h / 20 °C

8: 98 percent / 24 h / 20 °C

9: 43 percent / LiAlH₄ / tetrahydrofuran / 48 h / -78 °C

With 1H-imidazole; lithium aluminium tetrahydride; trimethylaluminum; silica gel; L-Selectride; sodium tris(acetoxy)borohydride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetic acid; ethyl acetate; Petroleum ether; 2: Cycloaddition / 3: Reduction / 4: Hydrolysis / 5: Reduction / 6: Ring cleavage / 7: Substitution / 8: Methylation / 9: Reduction;
DOI:10.1016/S0040-4020(99)00764-4

Reference yield:

: 77630-12-7
2-formyl-4,4-dimethylcyclohex-2-en-1-one

: 253446-47-8
2-methoxymethyl-6,6-dimethyl-2-cyclohexene-1-acetaldehyde

Guidance literature:: Multi-step reaction with 8 steps

1: 63 percent / CH₂Cl₂ / 240 h / 20 °C

2: 110 mg / L-selectride / tetrahydrofuran / 20 °C

3: 3.189 g / silica gel / diethyl ether; ethyl acetate; petroleum ether

4: 86 percent / NaBH(OAc)3 / acetic acid / 12 h / 20 °C

5: 96 percent / Me₃Al / hexane; CH₂Cl₂ / 0.5 h / 0 °C

6: 87 percent / imidazole / tetrahydrofuran / 14 h / 20 °C

7: 98 percent / 24 h / 20 °C

8: 43 percent / LiAlH₄ / tetrahydrofuran / 48 h / -78 °C

With 1H-imidazole; lithium aluminium tetrahydride; trimethylaluminum; silica gel; L-Selectride; sodium tris(acetoxy)borohydride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetic acid; ethyl acetate; Petroleum ether; 1: Cycloaddition / 2: Reduction / 3: Hydrolysis / 4: Reduction / 5: Ring cleavage / 6: Substitution / 7: Methylation / 8: Reduction;
DOI:10.1016/S0040-4020(99)00764-4