3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI)

Base Information

Chemical Name:3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI)
CAS No.:90762-16-6
Molecular Formula:C₈H₁₀O₄
Molecular Weight:170.165
Hs Code.:
Mol file:90762-16-6.mol

Synonyms:3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI)

Chemical Property:

Boiling Point:92 - 100 °C (0.05 mmHg)
PSA：55.76000
LogP:-0.69240

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI)

There total 4 articles about 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester,stereoisomer(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 81763-39-5,81800-81-9,92936-00-0,92936-01-1
exo-2,3-epoxy-6-methoxycarbonyl-7-oxabicyclo<2.2.1>heptane

: 90687-25-5,90762-16-6
3-hydroxy-6-methoxycarbonyl-7-oxa-tricyclo<2.2.1.0^2,6>heptane

Guidance literature:: With n-butyllithium; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; at -78 ℃; for 1h;
DOI:10.1016/S0040-4020(01)83498-0

Reference yield:

: 81763-39-5,81800-81-9,92936-00-0,92936-01-1
exo-2,3-epoxy-6-methoxycarbonyl-7-oxabicyclo<2.2.1>heptane

: 90687-25-5,90762-16-6
(1S,2S,4S,5R,6R)-5-Hydroxy-3-oxa-tricyclo[2.2.1.0^2,6]heptane-1-carboxylic acid methyl ester

: 78844-86-7,78961-89-4,83648-86-6,90866-42-5,90866-43-6
methyl cis-3,4-epoxy-5-hydroxy-cyclohexene-1-carboxylate

Guidance literature:: With lithium diisopropyl amide; at -78 ℃; Yield given;

Reference yield:

: 17791-32-1,17791-33-2,21987-33-7,88517-51-5,88517-52-6,204988-60-3
7-Oxabicyclo<2.2.1>hept-5-en-2-carbonsaeure-methylester

: 90687-25-5,90762-16-6
(1S,2S,4S,5R,6R)-5-Hydroxy-3-oxa-tricyclo[2.2.1.0^2,6]heptane-1-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: MCPBA

2: LDA / -78 °C

With 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide;