C₅₁H₈₀O₁₁SSi

Base Information

Chemical Name:C₅₁H₈₀O₁₁SSi
CAS No.:954106-35-5
Molecular Formula:C₅₁H₈₀O₁₁SSi
Molecular Weight:929.341
Hs Code.:

C<sub>51</sub>H<sub>80</sub>O<sub>11</sub>SSi

Synonyms:C₅₁H₈₀O₁₁SSi

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Chemical Property of C₅₁H₈₀O₁₁SSi

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Technology Process of C₅₁H₈₀O₁₁SSi

There total 25 articles about C₅₁H₈₀O₁₁SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 954106-34-4
C₄₅H₇₀O₁₁SSi

: 73541-16-9
5-iodo-2-methylpent-1-en

: 954106-35-5
C₅₁H₈₀O₁₁SSi

Guidance literature:: 5-iodo-2-methylpent-1-en; With tert.-butyl lithium; In diethyl ether; at -78 ℃; for 0.5h;

C₄₅H₇₀O₁₁SSi; In diethyl ether; for 0.333333h;

With pyridine; Dess-Martin periodane; In dichloromethane; for 0.333333h; Further stages.;
DOI:10.1016/j.tetlet.2007.07.182

Reference yield:

: 954106-23-1
C₃₇H₄₅NO₆

: 954106-35-5
C₅₁H₈₀O₁₁SSi

Guidance literature:: Multi-step reaction with 17 steps

1.1: 92 percent / LiOH*H₂O; aq. H₂O₂ / tetrahydrofuran / 2 h / 20 °C

2.1: 96 percent / H₂; K₂CO₃ / Pd/C / methanol / 0.83 h

3.1: EDC; DMAP / dimethylformamide / 12 h / 50 °C

4.1: ((S)-1-Ph-2-piperidin-1-yl-Et)-(2,2,2-triF-Et)amine; n-BuLi / tetrahydrofuran; hexane / 1 h

4.2: Me₃SiCl / 0.58 h / -78 - 0 °C

5.1: 0.310 g / LiAlH₄ / tetrahydrofuran / 5 h / Heating

6.1: n-Bu₂SnO / toluene / 0.75 h / Heating

6.2: 71 percent / CH₂Cl₂ / 1 h / 0 °C

7.1: imidazole / dimethylformamide / 3 h / 65 °C

7.2: dimethylformamide / 20 h / 80 °C

8.1: 0.174 g / DDQ / CH₂Cl₂; H₂O / 1.5 h / 20 °C

9.1: O₃; N-methylmorpholine N-oxide; benzyl ethyl eter / CH₂Cl₂ / 0.13 h / -78 °C

9.2: 80 percent / NaBH₄ / methanol / 1 h / -40 - -10 °C

10.1: DMSO; (COCl)2; Et₃N / CH₂Cl₂ / 1.67 h / -78 - 0 °C

11.1: 0.112 g / Bn₂NH*CF₃COOH / toluene / 16 h / 45 °C

12.1: NaBH₄ / ethanol / 1 h / -78 - 0 °C

12.2: aq. HF; pyridine / tetrahydrofuran / 9 h / 20 °C

12.3: 81 percent / i-Pr₂NEt; tetra-n-butylammonium iodide / CH₂Cl₂ / 10 h / 50 °C

13.1: 78 percent / EtOH / Raney Ni W-2 / 7 h

14.1: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

14.2: 11 mg / DIBAL / CH₂Cl₂; toluene / 1 h / -78 °C

15.1: 94 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h / 20 °C

16.1: t-BuLi / diethyl ether / 0.5 h / -78 °C

16.2: diethyl ether / 0.33 h

16.3: 86 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h

With pyridine; 1H-imidazole; dmap; lithium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; ethanol; hydrogen; dihydrogen peroxide; tert.-butyl lithium; di(n-butyl)tin oxide; potassium carbonate; Dess-Martin periodane; ozone; dimethyl sulfoxide; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; Raney Ni W-2; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; 4.1: Ireland-Claisen rearrngement / 10.1: Swern oxidation reaction;
DOI:10.1016/j.tetlet.2007.07.182

Reference yield:

: 954106-39-9
C₂₅H₃₁NO₄

: 954106-35-5
C₅₁H₈₀O₁₁SSi

Guidance literature:: Multi-step reaction with 18 steps

1.1: NaHDMS / tetrahydrofuran / 2 h / -78 °C

1.2: 80 percent / tetrahydrofuran / -78 - -20 °C

2.1: 92 percent / LiOH*H₂O; aq. H₂O₂ / tetrahydrofuran / 2 h / 20 °C

3.1: 96 percent / H₂; K₂CO₃ / Pd/C / methanol / 0.83 h

4.1: EDC; DMAP / dimethylformamide / 12 h / 50 °C

5.1: ((S)-1-Ph-2-piperidin-1-yl-Et)-(2,2,2-triF-Et)amine; n-BuLi / tetrahydrofuran; hexane / 1 h

5.2: Me₃SiCl / 0.58 h / -78 - 0 °C

6.1: 0.310 g / LiAlH₄ / tetrahydrofuran / 5 h / Heating

7.1: n-Bu₂SnO / toluene / 0.75 h / Heating

7.2: 71 percent / CH₂Cl₂ / 1 h / 0 °C

8.1: imidazole / dimethylformamide / 3 h / 65 °C

8.2: dimethylformamide / 20 h / 80 °C

9.1: 0.174 g / DDQ / CH₂Cl₂; H₂O / 1.5 h / 20 °C

10.1: O₃; N-methylmorpholine N-oxide; benzyl ethyl eter / CH₂Cl₂ / 0.13 h / -78 °C

10.2: 80 percent / NaBH₄ / methanol / 1 h / -40 - -10 °C

11.1: DMSO; (COCl)2; Et₃N / CH₂Cl₂ / 1.67 h / -78 - 0 °C

12.1: 0.112 g / Bn₂NH*CF₃COOH / toluene / 16 h / 45 °C

13.1: NaBH₄ / ethanol / 1 h / -78 - 0 °C

13.2: aq. HF; pyridine / tetrahydrofuran / 9 h / 20 °C

13.3: 81 percent / i-Pr₂NEt; tetra-n-butylammonium iodide / CH₂Cl₂ / 10 h / 50 °C

14.1: 78 percent / EtOH / Raney Ni W-2 / 7 h

15.1: Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

15.2: 11 mg / DIBAL / CH₂Cl₂; toluene / 1 h / -78 °C

16.1: 94 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h / 20 °C

17.1: t-BuLi / diethyl ether / 0.5 h / -78 °C

17.2: diethyl ether / 0.33 h

17.3: 86 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h

With pyridine; 1H-imidazole; dmap; lithium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; ethanol; hydrogen; dihydrogen peroxide; tert.-butyl lithium; sodium hexamethyldisilazane; di(n-butyl)tin oxide; potassium carbonate; Dess-Martin periodane; ozone; dimethyl sulfoxide; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; Raney Ni W-2; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; 5.1: Ireland-Claisen rearrngement / 11.1: Swern oxidation reaction;
DOI:10.1016/j.tetlet.2007.07.182