[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane
CAS No.:127065-37-6
Molecular Formula:C₂₀H₃₄O₃Si
Molecular Weight:350.574
Hs Code.:

Synonyms:[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

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Technology Process of [(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

There total 5 articles about [(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 127065-36-5,127128-07-8
(2R,3R,4S,5R)-5-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-hexane-1,2-diol

: 127065-37-6
[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: With sodium hydride; 1-(Trimethylsilyl)imidazole;
DOI:10.1021/jo00295a009

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 127065-37-6
[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 2) R₃N / 1) -78 deg C

2: NMO / OsO₄

With N-methyl-2-indolinone; osmium(VIII) oxide;
DOI:10.1021/jo00295a009

Reference yield:

: 127065-35-4
[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-methyl-but-3-enyloxy]-tert-butyl-dimethyl-silane

: 127065-37-6
[(1S,2R)-1-((R)-1-Benzyloxy-ethyl)-2-(R)-oxiranyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: NMO / OsO₄

With N-methyl-2-indolinone; osmium(VIII) oxide;
DOI:10.1021/jo00295a009