diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate

Base Information

• Chemical Name: diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate
• CAS No.: 934810-26-1
• Molecular Formula: C₂₇H₃₄O₈
• Molecular Weight: 486.562
• Mol file: 934810-26-1.mol

Synonyms:diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate

Chemical Property of diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate

There total 1 articles about diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

diallyl 2-(4-methoxycarbonylbenzyl)malonate (934737-76-5) + ethyl [1-(2-bromoethyl)cyclopropyl]acetate (934809-93-5) → diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate (934810-26-1)

Guidance literature:

diallyl 2-(4-methoxycarbonylbenzyl)malonate; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 40 ℃; Inert atmosphere;

ethyl [1-(2-bromoethyl)cyclopropyl]acetate; In N,N-dimethyl-formamide; mineral oil; at 40 - 100 ℃; Inert atmosphere;

Reference yield: 73.0%

diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate (934810-26-1) → 4-[1-(2-Ethoxy-2-oxoethyl)cyclopropyl]-2-[4-(methoxycarbonyl)benzyl]butanoic acid (934810-00-1)

Guidance literature:

diallyl {2-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]ethyl}[4-(methoxycarbonyl)benzyl]malonate; With formic acid; triethylamine; palladium diacetate; triphenylphosphine; In 1,4-dioxane; at 20 - 100 ℃;

With hydrogenchloride; water; In 1,4-dioxane;

upstream raw materials:

diallyl 2-(4-methoxycarbonylbenzyl)malonate

ethyl [1-(2-bromoethyl)cyclopropyl]acetate

Downstream raw materials:

4-[1-(2-Ethoxy-2-oxoethyl)cyclopropyl]-2-[4-(methoxycarbonyl)benzyl]butanoic acid