C₂₉H₃₄O₅Si

Base Information

• Chemical Name: C₂₉H₃₄O₅Si
• CAS No.: 1414494-75-9
• Molecular Formula: C₂₉H₃₄O₅Si
• Molecular Weight: 490.671
• Mol file: 1414494-75-9.mol

Synonyms:C₂₉H₃₄O₅Si

Chemical Property of C₂₉H₃₄O₅Si

Chemical Property:

Purity/Quality:

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Technology Process of C₂₉H₃₄O₅Si

There total 1 articles about C₂₉H₃₄O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl 3-(5-formylfuran-2-yl)propanoate (1304688-76-3) + 4-(tert-butyldiphenylsilyloxy)-1-butyne (88158-68-3) → C29H34O5Si (1414494-75-9)

Guidance literature:

4-(tert-butyldiphenylsilyloxy)-1-butyne; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

ethyl 3-(5-formylfuran-2-yl)propanoate; In tetrahydrofuran; at -78 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol302813e

Reference yield:

C29H34O5Si (1414494-75-9) → C27H36O4Si + C27H36O4Si

Guidance literature:

Multi-step reaction with 3 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 3 h / 20 °C / Inert atmosphere

2: diisobutylaluminium hydride / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

3: sodium acetate; sodium hydrogencarbonate; N-Bromosuccinimide / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

With N-Bromosuccinimide; palladium 10% on activated carbon; hydrogen; sodium acetate; diisobutylaluminium hydride; sodium hydrogencarbonate; In methanol; dichloromethane; 3: |Achmatowicz Reaction;

DOI:10.1021/ol302813e

upstream raw materials:

ethyl 3-(5-formylfuran-2-yl)propanoate

4-(tert-butyldiphenylsilyloxy)-1-butyne