Technology Process of C29H34O5Si
There total 1 articles about C29H34O5Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4-(tert-butyldiphenylsilyloxy)-1-butyne;
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 0.5h;
Inert atmosphere;
ethyl 3-(5-formylfuran-2-yl)propanoate;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 1h;
Inert atmosphere;
DOI:10.1021/ol302813e
- Guidance literature:
-
Multi-step reaction with 3 steps
1: palladium 10% on activated carbon; hydrogen / methanol / 3 h / 20 °C / Inert atmosphere
2: diisobutylaluminium hydride / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere
3: sodium acetate; sodium hydrogencarbonate; N-Bromosuccinimide / dichloromethane / 0.5 h / 0 °C / Inert atmosphere
With
N-Bromosuccinimide; palladium 10% on activated carbon; hydrogen; sodium acetate; diisobutylaluminium hydride; sodium hydrogencarbonate;
In
methanol; dichloromethane;
3: |Achmatowicz Reaction;
DOI:10.1021/ol302813e