C₂₄H₂₈O₅

Base Information

• Chemical Name: C₂₄H₂₈O₅
• CAS No.: 1431370-71-6
• Molecular Formula: C₂₄H₂₈O₅
• Molecular Weight: 396.483
• Mol file: 1431370-71-6.mol

Synonyms:C₂₄H₂₈O₅

Chemical Property of C₂₄H₂₈O₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₄H₂₈O₅

There total 9 articles about C₂₄H₂₈O₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pent-4-enyl 3,5-di-O-benzyl-β-D-ribofuranoside (1431370-51-2) → C24H28O5 (1431370-71-6)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 25 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol400931p

Reference yield:

pent-4-enyl 2-O-benzoyl-3,5-di-O-benzyl-β-D-ribofuranoside (1431370-46-5) → C24H28O5 (1431370-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium methylate / methanol / 2 h / 25 °C / Inert atmosphere

2: Dess-Martin periodane / dichloromethane / 2 h / 25 °C / Inert atmosphere

With sodium methylate; Dess-Martin periodane; In methanol; dichloromethane; 2: |Dess-Martin Oxidation;

DOI:10.1021/ol400931p

Reference yield:

3,5-di-O-benzoyl-α-D-ribofuranoside-prop-2-ynyl-1,2-orthobenzoate (66981-58-6) → C24H28O5 (1431370-71-6)

Guidance literature:

Multi-step reaction with 5 steps

1: sodium methylate / dichloromethane; methanol / 2 h / 20 °C / Inert atmosphere

2: sodium hydride / N,N-dimethyl-formamide; mineral oil / 2 h / 0 - 20 °C / Inert atmosphere

3: gold(III) chloride / dichloromethane / 2 h / 25 °C / Molecular sieve; Inert atmosphere

4: sodium methylate / methanol / 2 h / 25 °C / Inert atmosphere

5: Dess-Martin periodane / dichloromethane / 2 h / 25 °C / Inert atmosphere

With gold(III) chloride; sodium methylate; sodium hydride; Dess-Martin periodane; In methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil; 5: |Dess-Martin Oxidation;

DOI:10.1021/ol400931p

upstream raw materials:

pent-4-enyl 2-O-benzoyl-3,5-di-O-benzyl-β-D-ribofuranoside

3,5-di-O-benzoyl-α-D-ribofuranoside-prop-2-ynyl-1,2-orthobenzoate

pent-4-enyl 3,5-di-O-benzyl-β-D-ribofuranoside

3,5-di-O-benzyl-α-D-ribofuranoside (prop-2-yn-1-yl)-1,2-orthobenzoate

Downstream raw materials:

pent-4-enyl 3,5-di-O-benzyl-β-D-arabinofuranoside

Refernces