C₄₅H₆₅O₁₁N⁽¹³⁾C₄

Base Information

• Chemical Name: C₄₅H₆₅O₁₁N⁽¹³⁾C₄
• CAS No.: 1027818-14-9
• Molecular Formula: C₄₉H₆₅NO₁₁
• Molecular Weight: 848.011
• Mol file: 1027818-14-9.mol

Synonyms:C₄₅H₆₅O₁₁N⁽¹³⁾C₄

Chemical Property of C₄₅H₆₅O₁₁N⁽¹³⁾C₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₄₅H₆₅O₁₁N⁽¹³⁾C₄

There total 8 articles about C₄₅H₆₅O₁₁N⁽¹³⁾C₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

C13H19NO7(13)C4 (1027818-12-7) + 27-O-diethylphosphonoacetylmyricerone (186382-81-0) → C45H65O11N(13)C4 (1027818-14-9)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 20 ℃;

DOI:10.1002/jlcr.1240

Reference yield:

C12H13NO6 (1027818-09-2) → C45H65O11N(13)C4 (1027818-14-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 51 percent / H₂ / PtO₂ / ethyl acetate / 20 °C

2: 66 percent / PhNMe₂ / CH₂Cl₂ / 20 °C

3: 73 percent / DBU / acetonitrile / 20 °C

With hydrogen; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; platinum(IV) oxide; In dichloromethane; ethyl acetate; acetonitrile; 3: Wittig-Horner-Emmons reaction;

DOI:10.1002/jlcr.1240

Reference yield:

di-tert-butyl dicarbonate (24424-99-5) → C45H65O11N(13)C4 (1027818-14-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 89 percent / DMAP / acetonitrile / 20 °C

2: 51 percent / H₂ / PtO₂ / ethyl acetate / 20 °C

3: 66 percent / PhNMe₂ / CH₂Cl₂ / 20 °C

4: 73 percent / DBU / acetonitrile / 20 °C

With dmap; hydrogen; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; platinum(IV) oxide; In dichloromethane; ethyl acetate; acetonitrile; 4: Wittig-Horner-Emmons reaction;

DOI:10.1002/jlcr.1240

upstream raw materials:

C₁₃H₁₉NO₇⁽¹³⁾C₄

27-O-diethylphosphonoacetylmyricerone

[¹³C₄]dimethyl fumarate

CH₆O₄⁽¹³⁾C₄