E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)

Base Information

Chemical Name:E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)
CAS No.:883148-80-9
Molecular Formula:C₅₆H₆₀N₄O₄Zn
Molecular Weight:918.507
Hs Code.:

Synonyms:E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)

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Chemical Property of E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)

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Technology Process of E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)

There total 1 articles about E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 215313-78-3
[10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II)

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 883148-80-9
E,E-5,15-bis(2-methoxycarbonylethenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrinatozinc(II)

Guidance literature:: With di-tert-butylbiphenylphosphine; palladium diacetate; potassium carbonate; In N,N-dimethyl-formamide; toluene; under Ar; Zn complex, Pd acetate, phosphine and K2CO3 dried under vac.; dry DMF, dry toluene and methyl acrylate (50-fold excess) added; degassed via freeze-pump-thaw cycles; sealed; heated to 105°C; stirred for 15 h; monitored by TLC; diluted with toluene; washed (H2O); org. layer collected; dried; purified by column chromy. (silica gel, CHCl3-n-hexane 1:1, CHCl3-MeOH 99:1); second band collected; recrystd. from CHCl3(1% pyridine)-MeOH; elem. anal.;
DOI:10.1039/b516989e