Technology Process of C40H66O2Si
There total 8 articles about C40H66O2Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C40H68O2Si;
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -78 ℃;
for 0.333333h;
Inert atmosphere;
With
triethylamine;
In
dichloromethane;
at -78 - 20 ℃;
for 0.5h;
Inert atmosphere;
DOI:10.1021/tx300315h
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: hydrogen bromide / toluene
2.1: triphenylphosphine / acetonitrile / 90 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
3.2: 0.17 h / 0 °C / Inert atmosphere
4.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C
5.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
5.2: 0.5 h / -78 - 20 °C / Inert atmosphere
With
n-butyllithium; oxalyl dichloride; palladium 10% on activated carbon; hydrogen bromide; hydrogen; dimethyl sulfoxide; triphenylphosphine;
In
tetrahydrofuran; methanol; hexane; dichloromethane; toluene; acetonitrile;
DOI:10.1021/tx300315h
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 1H-imidazole / dichloromethane / 0.58 h / 20 °C
1.2: 0.17 h / 20 °C
2.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
2.2: 0.5 h / -78 - 20 °C / Inert atmosphere
3.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
3.2: 0.17 h / 0 °C / Inert atmosphere
4.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C
5.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
5.2: 0.5 h / -78 - 20 °C / Inert atmosphere
With
1H-imidazole; n-butyllithium; oxalyl dichloride; palladium 10% on activated carbon; hydrogen; dimethyl sulfoxide;
In
tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1021/tx300315h
