Titanium, 3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-3-pentanolatotrimethoxy-, (T-4)-

Base Information

• Chemical Name: Titanium, 3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-3-pentanolatotrimethoxy-, (T-4)-
• CAS No.: 94136-97-7
• Molecular Formula: C₁₆H₃₆O₄Ti
• Molecular Weight: 340.339
• Mol file: 94136-97-7.mol

Synonyms:3-Pentanol,3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-, titanium complex

Chemical Property of Titanium, 3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-3-pentanolatotrimethoxy-, (T-4)-

Chemical Property:

• PSA: 36.92000
• LogP: 4.63570

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Titanium, 3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-3-pentanolatotrimethoxy-, (T-4)-

There total 4 articles about Titanium, 3-(1,1-dimethylethyl)-2,2,4,4-tetramethyl-3-pentanolatotrimethoxy-, (T-4)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(OC(C(CH3)3)3)Ti(CH3)3 (89958-93-0) → (OC(C(CH3)3)3)Ti(OCH3)3 (94136-97-7)

Guidance literature:

Multi-step reaction with 3 steps

1: O₂ / benzene-d6

2: benzene-d6

3: O₂ / benzene-d6

With O₂; In benzene-d6;

DOI:10.1021/ja00236a021

Reference yield:

(OC(C(CH3)3)3)Ti(CH3)2(OCH3) (94136-95-5) → (OC(C(CH3)3)3)Ti(OCH3)3 (94136-97-7)

Guidance literature:

With O₂; In benzene-d6; oxygenation of metal complex in C6D6 with 1 atm of O2 (1 h, sealed NMR tube); not isolated, detd. by NMR;

DOI:10.1021/ja00236a021

Reference yield:

(OC(C(CH3)3)3)Ti(CH3)(OCH3)2 (94136-96-6) → (OC(C(CH3)3)3)Ti(OCH3)3 (94136-97-7)

Guidance literature:

With O₂; In benzene-d6; oxygenation of metal complex in C6D6 with 1 atm of O2 (8 h, sealed NMR tube); not isolated, detd. by NMR;

DOI:10.1021/ja00236a021

upstream raw materials:

(OC(C(CH₃)3)3)Ti(CH₃)3

oxygen

(OC(C(CH₃)3)3)Ti(CH₃)2(OCH₃)

(OC(C(CH₃)3)3)Ti(CH₃)(OCH₃)2

Refernces

• 1、 Lubben, Timothy V.,Wolczanski, Peter T.. "Dioxygen Activation by Group 4 tritox Alkyls (tritox = t-Bu3CO-): Insrtion and Oxygen Atom Transfer". . p. 424 - 435. Retrieved 2007/10/02.