[palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)]

Base Information

• Chemical Name: [palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)]
• CAS No.: 211241-08-6
• Molecular Formula: C₂₄H₄₇BrN₂OPdSi
• Molecular Weight: 594.059
• Mol file: 211241-08-6.mol

Synonyms:[palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)]

Chemical Property of [palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)]

There total 1 articles about [palladium(bromide)(tetramethylethylenediamine)(CH₂C₆H₂(t-Bu)2OSiMe₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) + [4-(Bromomethyl)-2,6-di-tert-butylphenoxy]trimethylsilylane (211241-07-5) → [palladium(bromide)(tetramethylethylenediamine)(CH2C6H2(t-Bu)2OSiMe3)] (211241-08-6)

Guidance literature:

In acetone; cooling;

DOI:10.1021/ja9809612

Reference yield:

[palladium(bromide)(tetramethylethylenediamine)(CH2C6H2(t-Bu)2OSiMe3)] (211241-08-6) → [palladium(1,2-bis(diphenylphosphine)ethane)(η2-CH2C6H2(t-Bu)2)O] (211241-10-0)

Guidance literature:

Multi-step reaction with 2 steps

2: (n-Bu)4NF*3H₂O / tetrahydrofuran

With (n-Bu)4NF*3H₂O; In tetrahydrofuran;

DOI:10.1021/ja9809612

Reference yield:

[palladium(bromide)(tetramethylethylenediamine)(CH2C6H2(t-Bu)2OSiMe3)] (211241-08-6) → [palladium(1,2-bis(diphenylphosphine)ethane)(η2-CH2C6H2(t-Bu)2OMe)](triflate)

Guidance literature:

Multi-step reaction with 2 steps

1: tetra(tert-butyl)-ammonium fluoride / Inert atmosphere; Schlenk technique

2: toluene / 0.67 h / -30 - 20 °C / Inert atmosphere; Schlenk technique

With tetra(tert-butyl)-ammonium fluoride; In toluene;

DOI:10.1021/om400523f

upstream raw materials:

[4-(Bromomethyl)-2,6-di-tert-butylphenoxy]trimethylsilylane

Downstream raw materials:

[palladium(bromide)(1,2-bis(diphenylphosphine)ethane)(CH₂C₆H₂(t-Bu)2OSiMe₃)]

[palladium(1,2-bis(diphenylphosphine)ethane)(η²-CH2C6H2(t-Bu)2)O]

[palladium(1,3-bis(di-tert-butylphosphine)propane)(CH₂C₆H₂(t-Bu)2OMe)(triflate)]