1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone

Base Information

• Chemical Name: 1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone
• CAS No.: 148058-52-0
• Molecular Formula: C₁₈H₂₄N₄O₄
• Molecular Weight: 360.413
• Mol file: 148058-52-0.mol

Synonyms:1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone

Chemical Property of 1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone

There total 2 articles about 1,7,11,17-Tetraaza-tricyclo[15.3.1.1^7,11]docosa-9,18-diene-8,20,21,22-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

1,5-dibromo-pentane (111-24-0) + uracil (66-22-8,144104-68-7,18324-22-6,27072-01-1,2920-92-5,51953-19-6) → 1,7,11,17-Tetraaza-tricyclo[15.3.1.17,11]docosa-9,19-diene-8,18,21,22-tetraone (148058-43-9) + 1,7,11,17-Tetraaza-tricyclo[15.3.1.17,11]docosa-9,18-diene-8,20,21,22-tetraone (148058-52-0)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; a) RT, 15 h, b) 70 deg C, 3 h;

DOI:10.1246/bcsj.69.3239

Reference yield: 7.0%

1,5-diiodopentane (628-77-3) + uracil (66-22-8,144104-68-7,18324-22-6,27072-01-1,2920-92-5,51953-19-6) → 1,7,11,17-Tetraaza-tricyclo[15.3.1.17,11]docosa-9,19-diene-8,18,21,22-tetraone (148058-43-9) + 1,7,11,17-Tetraaza-tricyclo[15.3.1.17,11]docosa-9,18-diene-8,20,21,22-tetraone (148058-52-0)

Guidance literature:

With sodium hydride; N,N-dimethyl-formamide; a) RT, 15 h, b) 70 deg C, 3 h;

DOI:10.1246/cl.1993.233

Reference yield: 20.0%

N-phenyl-maleimide (941-69-5) + 1,7,11,17-Tetraaza-tricyclo[15.3.1.17,11]docosa-9,18-diene-8,20,21,22-tetraone (148058-52-0) → 9-(2,5-Dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)-1,7,11,17-tetraaza-tricyclo[15.3.1.17,11]docosa-9,18-diene-8,20,21,22-tetraone + 9,19-Bis-(2,5-dioxo-1-phenyl-2,5-dihydro-1H-pyrrol-3-yl)-1,7,11,17-tetraaza-tricyclo[15.3.1.17,11]docosa-9,18-diene-8,20,21,22-tetraone

Guidance literature:

With palladium diacetate; In acetic acid; at 100 - 110 ℃; for 14h;

DOI:10.1246/bcsj.69.3239

upstream raw materials:

1,5-diiodopentane

uracil

1,5-dibromo-pentane