methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

Base Information

Chemical Name:methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside
CAS No.:139391-39-2
Molecular Formula:C₂₁H₃₆O₅Si
Molecular Weight:396.599
Hs Code.:

Synonyms:methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

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Chemical Property of methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

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Technology Process of methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

There total 10 articles about methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 139391-38-1
methyl 5-O-acetyl-2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

: 139391-39-2
methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

Guidance literature:: With potassium carbonate; In methanol; at 60 ℃; for 36h;
DOI:10.1016/S0040-4020(01)91030-0

Reference yield:

: 139391-38-1,139391-59-6
(+/-)-methyl 5-O-acetyl-2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

: 139391-39-2,139391-60-9
(+/-)-methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

Guidance literature:: With potassium carbonate; In methanol; at 60 ℃; for 36h;
DOI:10.1016/S0040-4020(01)91030-0

Reference yield:

: 139391-35-8
2-((2S,3S,4R,5R)-4-Benzyloxy-3-hydroxy-5-methoxy-tetrahydro-furan-2-yl)-2-methyl-propionic acid methyl ester

: 139391-39-2
methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-<(t-butyl)dimethylsilyl>-α-L-arabino-hexofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide / 96 h / 55 °C

2: 2) MeOH / 1) pentane, THF, up to -20 deg C, 30 min, 2) -15 deg C, 20 min

3: 69 percent / CF₃CO₃H, Na₂HPO₄ / CH₂Cl₂ / 4 h / 20 °C

4: 90 percent / K₂CO₃ / methanol / 36 h / 60 °C

With 1H-imidazole; methanol; disodium hydrogenphosphate; trifluoroacetyl peroxide; potassium carbonate; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)91030-0