N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

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Chemical Name:N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine
CAS No.:852104-86-0
Molecular Formula:C₂₈H₄₃NO₃Si
Molecular Weight:469.74
Hs Code.:

Synonyms:N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

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Chemical Property of N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

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Technology Process of N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

There total 7 articles about N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: N-(methoxycarbonyl)-4-(1-cyclohexenyl)-3-butynylamine

: 852105-18-1
1-bromo-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiyne

: 852104-86-0
N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

Guidance literature:: N-(methoxycarbonyl)-4-(1-cyclohexenyl)-3-butynylamine; With potassium hexamethylsilazane; In tetrahydrofuran; pyridine; at 0 ℃; for 0.166667h;

With copper(l) iodide; In tetrahydrofuran; pyridine; at 0 - 20 ℃;

1-bromo-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiyne; In tetrahydrofuran; pyridine; benzene; at 20 ℃; for 20h;
DOI:10.1021/ja051180l

Reference yield:

: 852104-71-3
N-(methoxycarbonyl)-3-butynylamine

: 852104-86-0
N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: 75 percent / (Ph₃P)2PdCl₂; CuI / tetrahydrofuran; pyridine / 2 h / 20 °C

2.1: KHMDS / pyridine; tetrahydrofuran / 0.17 h / 0 °C

2.2: CuI / pyridine; tetrahydrofuran / 0 - 20 °C

2.3: 51 percent / pyridine; tetrahydrofuran; benzene / 20 h / 20 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hexamethylsilazane; In tetrahydrofuran; pyridine;
DOI:10.1021/ja051180l

Reference yield:

: 852105-17-0
(1,1-dimethyl-penta-2,4-diynyloxy)-triisopropyl-silane

: 852104-86-0
N-(methoxycarbonyl)-N-[4-(1-cyclohexenyl)-3-butynyl]-5-(triisopropylsiloxy)-5-methyl-1,3-hexadiynylamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: 98 percent / NBS; silver(I) nitrate / acetone / 20 h / 20 °C

2.1: KHMDS / pyridine; tetrahydrofuran / 0.17 h / 0 °C

2.2: CuI / pyridine; tetrahydrofuran / 0 - 20 °C

2.3: 51 percent / pyridine; tetrahydrofuran; benzene / 20 h / 20 °C

With N-Bromosuccinimide; potassium hexamethylsilazane; silver nitrate; In tetrahydrofuran; pyridine; acetone;
DOI:10.1021/ja051180l