[5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II)

Base Information

• Chemical Name: [5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II)
• CAS No.: 586330-68-9
• Molecular Formula: C₅₈H₄₂N₆O₄Zn
• Molecular Weight: 952.399
• Mol file: 586330-68-9.mol

Synonyms:[5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II)

Chemical Property of [5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II)

There total 1 articles about [5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(5-ethynyl-10,20-diphenyldiporphinato)zinc(II) (156821-63-5) + N-(4-iodophenyl)-N'-(n-octyl)-pyromellitic diimide (583879-92-9) → [5-[4'-(N-(N'-octyl)pyromellitic diimide)phenyl]ethynyl-10,20-diphenylporphirinato] zinc(II) (586330-68-9)

Guidance literature:

With diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; acetonitrile; under N2 atm. Zn complex, aryl halide, and Pd(PPh3)2Cl2 were combined inmixt. THF:MeCN:i-Pr2NH (1:1:1) and stirred at 40°C for 12-24 h; react. mixt. was cooled to room temp., diluted with CHCl3, washed with aq. NH4Cl, water, aq. NaCl, dried over MgSO4, and purified by chromy. on silica;

DOI:10.1021/ja021278p

upstream raw materials:

(5-ethynyl-10,20-diphenyldiporphinato)zinc(II)

N-(4-iodophenyl)-N'-(n-octyl)-pyromellitic diimide