((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

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Chemical Name:((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol
CAS No.:180063-01-8
Molecular Formula:C₂₆H₃₆O₄Si
Molecular Weight:440.655
Hs Code.:

Synonyms:((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

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Chemical Property of ((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

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Technology Process of ((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

There total 6 articles about ((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 180063-00-7
(Z)-5-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-methyl-pent-2-en-1-ol

: 180063-01-8
((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; 4 A molecular sieve; (+)-Weinsaeure-diethylester; In dichloromethane; at -22 ℃; for 0.5h;
DOI:10.1016/0040-4020(96)00453-X

Reference yield:

: 106-25-2
Nerol

: 180063-01-8
((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / pyridine / CH₂Cl₂ / 0.67 h

2: 1.) SeO₂, tert-butylhydroperoxide, 2.) NaBH₄ / 1.) CH₂Cl₂, 3 h, 2.) CH₂Cl₂, EtOH, -35 deg C, 1.5 h

3: 87 percent / titanium tetraisopropoxide, (+)-diethyl tartrate, tert-butylhydroperoxide, 4 A molecular sieves / CH₂Cl₂ / 0.5 h / -20 °C

4: imidazole / dimethylformamide / 13 h / Ambient temperature

5: aq. K₂CO₃ / methanol / 2.5 h

6: 88 percent / titanium tetraisopropoxide, (+)-diethyl tartrate, tert-butylhydroperoxide, 4 A molecular sieves / CH₂Cl₂ / 0.5 h / -22 °C

With pyridine; 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; selenium(IV) oxide; 4 A molecular sieve; potassium carbonate; (+)-Weinsaeure-diethylester; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(96)00453-X

Reference yield:

: 141-12-8,8022-83-1
neryl acetate

: 180063-01-8
((2S,3R)-3-{2-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-3-methyl-oxiranyl]-ethyl}-3-methyl-oxiranyl)-methanol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) SeO₂, tert-butylhydroperoxide, 2.) NaBH₄ / 1.) CH₂Cl₂, 3 h, 2.) CH₂Cl₂, EtOH, -35 deg C, 1.5 h

2: 87 percent / titanium tetraisopropoxide, (+)-diethyl tartrate, tert-butylhydroperoxide, 4 A molecular sieves / CH₂Cl₂ / 0.5 h / -20 °C

3: imidazole / dimethylformamide / 13 h / Ambient temperature

4: aq. K₂CO₃ / methanol / 2.5 h

5: 88 percent / titanium tetraisopropoxide, (+)-diethyl tartrate, tert-butylhydroperoxide, 4 A molecular sieves / CH₂Cl₂ / 0.5 h / -22 °C

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; selenium(IV) oxide; 4 A molecular sieve; potassium carbonate; (+)-Weinsaeure-diethylester; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(96)00453-X