[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

Base Information

Chemical Name:[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester
CAS No.:859507-90-7
Molecular Formula:C₁₈H₂₃NO₅
Molecular Weight:333.384
Hs Code.:

[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid <i>tert</i>-butyl ester

Synonyms:[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

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Chemical Property of [5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

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Technology Process of [5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

There total 1 articles about [5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 151978-50-6
N-(tert-butoxycarbonyl)-pent-4-ynyl-1-amine

: 685895-45-8
2-bromo-4,6-dihydroxy-5-methylbenzaldehyde

: 859507-90-7
[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In N,N-dimethyl-formamide; at 60 ℃; for 14h;
DOI:10.1021/ja052049g

Reference yield:

: 859507-90-7
[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

: (5-{(R)-4-Hydroxy-6-[1-hydroxy-meth-(Z)-ylidene]-4-methyl-3,5-dioxo-cyclohex-1-enyl}-pent-4-ynyl)-carbamic acid tert-butyl ester

Guidance literature:: With Cu₂[(-)-sparteine]2O₂; oxygen; N-ethyl-N,N-diisopropylamine; dmap; In dichloromethane; at -10 ℃; for 30h;
DOI:10.1021/ja052049g

Reference yield:

: 859507-90-7
[5-(2-formyl-3,5-dihydroxy-4-methyl-phenyl)-pent-4-ynyl]-carbamic acid tert-butyl ester

: 1013890-98-6
C₂₇H₃₁NO₇

Guidance literature:: Multi-step reaction with 3 steps

1: Au(OAc)3 / 1,2-dichloro-ethane / 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / 20 °C / Inert atmosphere

3: polystyrene supported 4-dimethylaminopyridine / dichloromethane / Inert atmosphere

With Au(OAc)3; tetrabutyl ammonium fluoride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/co300002x