4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

Base Information

Chemical Name:4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante
CAS No.:152560-36-6
Molecular Formula:C₂₁H₃₀N₂O₆SSi
Molecular Weight:466.63
Hs Code.:

Synonyms:4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

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Chemical Property of 4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

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Technology Process of 4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

There total 5 articles about 4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillanate (1RS)-oxide

: 152560-36-6
4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

Guidance literature:: With pyridine; tetraphosphorus decasulfide; In dichloromethane; for 8h;

Reference yield: 5.0%

: 152560-42-4
(3S,4R)-3-<(R)-1-tert-butyldimethylsilyloxyethyl>-4-<2-diazo-2-(4-nitrobenzyloxycarbonyl)ethyl>thio-2-azetidinone

: (3S,4R)-3-<(R)-1-tert-butyldimethylsilyloxyethyl>-4-<1-(4-nitrobenzyloxycarbonyl)ethenyl>thio-2-azetidinone

: 152560-36-6
4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

Guidance literature:: With dirhodium tetraacetate; In benzene; for 2h;

Reference yield:

: 152560-41-3
(3S,4R)-3-<(R)-1-tert-butyldimethylsilyloxyethyl>-4-<(R)-2-amino-2-(4-nitrobenzyloxycarbonyl)ethyl>thio-2-azetidinone

: 152560-36-6
4-nitrobenzyl (3S,5R,6S)-6-<(R)-1-tert-butyldimethylsilyloxyethyl>-3-(2,2-bisnor)penicillante

Guidance literature:: Multi-step reaction with 2 steps

1: 16.45 g / tert-butyl nitrate, acetic acid / CH₂Cl₂ / 1.5 h / Heating

2: 5 percent / Rh₂(OAc)4 / benzene / 2 h

With dirhodium tetraacetate; tert-butyl nitrate; acetic acid; In dichloromethane; benzene;