C₄₅H₆₄O₉Si

Base Information

Chemical Name:C₄₅H₆₄O₉Si
CAS No.:1592771-32-8
Molecular Formula:C₄₅H₆₄O₉Si
Molecular Weight:777.083
Hs Code.:

C<sub>45</sub>H<sub>64</sub>O<sub>9</sub>Si

Synonyms:C₄₅H₆₄O₉Si

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Chemical Property of C₄₅H₆₄O₉Si

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Technology Process of C₄₅H₆₄O₉Si

There total 34 articles about C₄₅H₆₄O₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 1592772-03-6
C₄₅H₆₃BrO₈Si

: 1592771-32-8
C₄₅H₆₄O₉Si

: 1592771-35-1
C₄₅H₆₄O₉Si

Guidance literature:: With 18-crown-6 ether; sodium hydroxide; In tetrahydrofuran; water; at 0 ℃; for 8h;
DOI:10.1021/ol500788c

Reference yield:

: methyl 3,5-O-di(tert-butyl)silylene-2-deoxy-D-ribofuranoside

: 1592771-32-8
C₄₅H₆₄O₉Si

Guidance literature:: Multi-step reaction with 17 steps

1.1: boron trifluoride diethyl etherate / dichloromethane / 1 h / 0 °C / Inert atmosphere

2.1: 4-methyl-morpholine / dichloromethane / 1 h / 20 °C / Inert atmosphere

3.1: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 21 h / 20 °C

4.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -20 °C / Inert atmosphere

5.1: lithium borohydride / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

6.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.33 h / 0 °C / Inert atmosphere

6.2: 1 h / 0 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C

8.1: 1H-imidazole / N,N-dimethyl-formamide / 1.5 h / 0 °C / Inert atmosphere

9.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.67 h / -78 °C / Inert atmosphere

9.2: 0.25 h / -78 °C / Inert atmosphere

10.1: diethyl ether / 0.33 h / -80 °C / Inert atmosphere

11.1: hydrogenchloride / methanol / 21 h / 20 °C

12.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / -80 °C / Inert atmosphere

13.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / -80 - 0 °C / Inert atmosphere

14.1: n-butyllithium / tetrahydrofuran; hexane; N,N,N,N,N,N-hexamethylphosphoric triamide / 0.67 h / -100 °C / Inert atmosphere

15.1: toluene-4-sulfonic acid / dichloromethane; methanol / 0.5 h / 20 °C

16.1: lithium bromide; magnesium bromide diethyl etherate / dichloromethane / 3 h / -15 - 0 °C / Inert atmosphere

17.1: sodium hydroxide; 18-crown-6 ether / tetrahydrofuran; water / 8 h / 0 °C

With 4-methyl-morpholine; 1H-imidazole; 2,6-dimethylpyridine; hydrogenchloride; lithium borohydride; n-butyllithium; samarium diiodide; magnesium bromide diethyl etherate; oxalyl dichloride; 18-crown-6 ether; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; potassium hexamethylsilazane; sodium hydrogencarbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; lithium bromide; sodium hydroxide; methyl iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 2.1: |Michael Addition / 17.1: |Favorskii Rearrangement;
DOI:10.1021/ol500788c

Reference yield:

: 1592771-15-7
C₁₆H₃₂O₃S₂Si

: 1592771-32-8
C₄₅H₆₄O₉Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: 4-methyl-morpholine / dichloromethane / 1 h / 20 °C / Inert atmosphere

2.1: methyl iodide; sodium hydrogencarbonate / acetonitrile; water / 21 h / 20 °C

3.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -20 °C / Inert atmosphere

4.1: lithium borohydride / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

5.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.33 h / 0 °C / Inert atmosphere

5.2: 1 h / 0 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C

7.1: 1H-imidazole / N,N-dimethyl-formamide / 1.5 h / 0 °C / Inert atmosphere

8.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.67 h / -78 °C / Inert atmosphere

8.2: 0.25 h / -78 °C / Inert atmosphere

9.1: diethyl ether / 0.33 h / -80 °C / Inert atmosphere

10.1: hydrogenchloride / methanol / 21 h / 20 °C

11.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / -80 °C / Inert atmosphere

12.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / -80 - 0 °C / Inert atmosphere

13.1: n-butyllithium / tetrahydrofuran; hexane; N,N,N,N,N,N-hexamethylphosphoric triamide / 0.67 h / -100 °C / Inert atmosphere

14.1: toluene-4-sulfonic acid / dichloromethane; methanol / 0.5 h / 20 °C

15.1: lithium bromide; magnesium bromide diethyl etherate / dichloromethane / 3 h / -15 - 0 °C / Inert atmosphere

16.1: sodium hydroxide; 18-crown-6 ether / tetrahydrofuran; water / 8 h / 0 °C

With 4-methyl-morpholine; 1H-imidazole; 2,6-dimethylpyridine; hydrogenchloride; lithium borohydride; n-butyllithium; samarium diiodide; magnesium bromide diethyl etherate; oxalyl dichloride; 18-crown-6 ether; tetrabutyl ammonium fluoride; potassium hexamethylsilazane; sodium hydrogencarbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; lithium bromide; sodium hydroxide; methyl iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 1.1: |Michael Addition / 16.1: |Favorskii Rearrangement;
DOI:10.1021/ol500788c