{(R,R),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

Base Information

Chemical Name:{(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate
CAS No.:122270-82-0
Molecular Formula:0CH₂Cl₂*C₃₉H₄₀FeP₃*F₆P
Molecular Weight:844.945
Hs Code.:

{(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

Synonyms:{(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

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Chemical Property of {(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

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Technology Process of {(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

There total 4 articles about {(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: ammonium hexafluorophosphate

: 122270-80-8
{(R*,R*),(S*)}-(+/-)-(benzylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate

: 865-47-4
potassium tert-butylate

: 122270-82-0
{(R*,R*),(S*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

Guidance literature:: With CH₃I; In tetrahydrofuran; dichloromethane; under Ar, cooling soln. of ((R*,R*),(S*))-4 in THF to -95°C, addn. of KOBu-t, after 5 min addn. of CH3I, warming to room temp., evapn. of solvent, dissolving in CH2Cl2, addn. of 5% aq. NH4PF6, shaking, several min; sepg. org. layer, drying over MgSO4, concg., dilg. with diethyl ether; elem. anal.;

Reference yield: 84.0%

: ammonium hexafluorophosphate

: 122270-80-8
{(R*,R*),(R*)}-(+/-)-(benzylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate monodichloromethane solvate

: 865-47-4
potassium tert-butylate

: 122270-82-0
{(R*,R*),(R*)}-(+/-)-(benzylmethylphenylphosphine)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

Guidance literature:: With CH₃I; In tetrahydrofuran; dichloromethane; under Ar, cooling soln. of ((R*,R*),(S*))-4 in THF to -95°C, addn. of KOBu-t, after 5 min addn. of CH3I, warming to room temp., evapn. of solvent, dissolving in CH2Cl2, addn. of 5% aq. NH4PF6, shaking, several min; sepg. org. layer, drying over MgSO4, concg., dilg. with diethyl ether; elem. anal.;