2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester

Base Information

Chemical Name:2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester
CAS No.:869661-36-9
Molecular Formula:C₁₄H₂₂O₅
Molecular Weight:270.326
Hs Code.:
Mol file:869661-36-9.mol

Synonyms:9-[2-(Methoxycarbonyl)vinyl]-9-methyl-7,8,12-trioxaspiro[5.6]dodecane

Suppliers and Price of 2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester

Chemical Property:

Purity/Quality:

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Technology Process of 2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester

There total 3 articles about 2-Propenoic acid, 3-(9-methyl-7,8,12-trioxaspiro[5.6]dodec-9-yl)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 918902-01-9
9-methyl-7,8,12-trioxa-spiro[5.6]dodecane-9-carbaldehyde

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 869661-36-9
(E)-3-(9-Methyl-7,8,12-trioxa-spiro[5.6]dodec-9-yl)-acrylic acid methyl ester

Guidance literature:: In dichloromethane; at 20 ℃; for 3h;
DOI:10.1016/j.bmcl.2006.08.098

Reference yield:

: 869661-31-4
9-(4-chloro-phenylsulfanylmethyl)-9-methyl-7,8,12-trioxa-spiro[5.6]dodecane

: 869661-36-9
(E)-3-(9-Methyl-7,8,12-trioxa-spiro[5.6]dodec-9-yl)-acrylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / m-CPBA / CH₂Cl₂ / 6 h / 20 °C

2: 83 percent / 2,6-lutidine; trifluoroacetic anhydride / acetonitrile / 20 °C

3: 62 percent / CH₂Cl₂ / 3 h / 20 °C

With 2,6-dimethylpyridine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride; In dichloromethane; acetonitrile; 3: Wittig reaction;
DOI:10.1016/j.bmcl.2006.08.098

Reference yield:

: 918901-94-7
9-(4-chloro-benzenesulfinylmethyl)-9-methyl-7,8,12-trioxa-spiro[5.6]dodecane

: 869661-36-9
(E)-3-(9-Methyl-7,8,12-trioxa-spiro[5.6]dodec-9-yl)-acrylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / 2,6-lutidine; trifluoroacetic anhydride / acetonitrile / 20 °C

2: 62 percent / CH₂Cl₂ / 3 h / 20 °C

With 2,6-dimethylpyridine; trifluoroacetic anhydride; In dichloromethane; acetonitrile; 2: Wittig reaction;
DOI:10.1016/j.bmcl.2006.08.098