2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone

Base Information

• Chemical Name: 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone
• CAS No.: 105147-38-4
• Molecular Formula: C₅₃H₃₈N₄O₃
• Molecular Weight: 778.91

Synonyms:2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone

Chemical Property of 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone

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Technology Process of 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone

There total 3 articles about 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

5-(4-hydroxyphenyl)-10,15,20-tri(p-tolyl)porphyrin (57412-08-5) + p-benzoquinone (106-51-4) → 2-[4-((1Z,4Z,9Z,15Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone (105147-38-4)

Guidance literature:

In chloroform; for 10h; Product distribution; Irradiation; also other porphyrins and quinones;

DOI:10.1039/c39870000359

Reference yield:

5-(4-hydroxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin (57412-08-5) + p-benzoquinone (106-51-4) → 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone (105147-38-4) + hydroquinone (123-31-9,8027-02-9)

Guidance literature:

In acetonitrile; benzene; Irradiation;

DOI:10.1246/cl.1986.475

Reference yield:

2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-benzene-1,4-diol (105147-39-5) + p-benzoquinone (106-51-4) → 2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-[1,4]benzoquinone (105147-38-4) + hydroquinone (123-31-9,8027-02-9)

Guidance literature:

In benzene; Irradiation;

DOI:10.1246/cl.1986.475

upstream raw materials:

5-(4-hydroxyphenyl)-10,15,20-tri(p-tolyl)porphyrin

p-benzoquinone

5-(4-hydroxyphenyl)-10,15,20-tris(4-methylphenyl)porphyrin

2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-benzene-1,4-diol

Downstream raw materials:

2-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-benzene-1,4-diol

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