cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Base Information

Chemical Name:cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine
CAS No.:1151538-46-3
Molecular Formula:C₃₂H₂₇NO₂S₂
Molecular Weight:521.704
Hs Code.:

Synonyms:cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Chemical Property of cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Technology Process of cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

There total 1 articles about cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: C₁₈H₁₅NOS

: 1151538-22-5
(S)-dimethyl[2-(p-toluenesulfinyl)phenyl]sulfonium perchlorate

: 1151538-54-3
trans-(2S,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1151538-46-3
cis-(2R,3S)-2-(2-naphthyl)-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Guidance literature:: (S)-dimethyl[2-(p-toluenesulfinyl)phenyl]sulfonium perchlorate; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.166667h; Inert atmosphere;

C₁₈H₁₅NOS; In tetrahydrofuran; at -78 ℃; for 0.166667h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo900381b