(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

Base Information

Chemical Name:(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal
CAS No.:910662-39-4
Molecular Formula:C₃₅H₄₂O₄Si
Molecular Weight:554.802
Hs Code.:

Synonyms:(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

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Chemical Property of (2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

Chemical Property:

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Technology Process of (2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

There total 11 articles about (2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: tert-Butyl-[(5E,7E)-8-(3,5-dimethoxy-phenyl)-1-((E)-3,3-dimethoxy-propenyl)-octa-5,7-dienyloxy]-diphenyl-silane

: 910662-39-4
(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

Guidance literature:: With Amberlyst 15; In acetone; at 23 ℃; for 0.666667h;
DOI:10.1002/anie.200601418

Reference yield:

: 910662-13-4
(4E,6E)-7-(3,5-dimethoxyphenyl)hepta-4,6-dien-1-ol

: 910662-39-4
(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

Guidance literature:: Multi-step reaction with 5 steps

1.1: 98 percent / triethylamine / CH₂Cl₂ / 1 h / -30 °C

2.1: 93 percent / NaI / acetone / 24 h / 23 °C

3.1: n-BuLi / diethyl ether; hexane / 0.75 h / -80 °C

3.2: 60 percent / diethyl ether; hexane / 0.25 h / -80 °C

4.1: imidazole / CH₂Cl₂ / 24 h / 20 °C

5.1: 203 mg / Amberlyst 15 / acetone / 0.67 h / 23 °C

With 1H-imidazole; n-butyllithium; Amberlyst 15; triethylamine; sodium iodide; In diethyl ether; hexane; dichloromethane; acetone;
DOI:10.1002/anie.200601418

Reference yield:

: 910662-14-5
1-[(1E,3E)-7-iodohepta-1,3-dienyl]-3,5-dimethoxybenzene

: 910662-39-4
(2E,8E,10E)-4-{[tert-butyl(diphenyl)silyl]oxy}-11-(3,5-dimethoxyphenyl)undeca-2,8,10-trienal

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi / diethyl ether; hexane / 0.75 h / -80 °C

1.2: 60 percent / diethyl ether; hexane / 0.25 h / -80 °C

2.1: imidazole / CH₂Cl₂ / 24 h / 20 °C

3.1: 203 mg / Amberlyst 15 / acetone / 0.67 h / 23 °C

With 1H-imidazole; n-butyllithium; Amberlyst 15; In diethyl ether; hexane; dichloromethane; acetone;
DOI:10.1002/anie.200601418