Technology Process of C21H34O3Si
There total 6 articles about C21H34O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
(3-methoxypent-4-yn-1-yl)benzene;
With
n-butyllithium;
In
diethyl ether; hexane;
at -40 ℃;
for 0.5h;
Inert atmosphere;
With
diethylaluminium chloride;
In
diethyl ether; hexane;
at -40 - 0 ℃;
Inert atmosphere;
(cis)-3-tert-butyldimethylsilyl-2,3-epoxypropan-1-ol;
In
diethyl ether; hexane; toluene;
at -40 - 23 ℃;
Inert atmosphere;
DOI:10.1021/ol202649j
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 23 °C / Inert atmosphere
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -40 °C / Inert atmosphere
2.2: -40 - 0 °C / Inert atmosphere
2.3: -40 - 23 °C / Inert atmosphere
With
n-butyllithium; 3-chloro-benzenecarboperoxoic acid;
In
diethyl ether; hexane; dichloromethane;
DOI:10.1021/ol202649j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: tetrahydrofuran / 0 - 23 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: -78 - 23 °C / Inert atmosphere
3.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -40 °C / Inert atmosphere
3.2: -40 - 0 °C / Inert atmosphere
3.3: -40 - 23 °C / Inert atmosphere
With
n-butyllithium;
In
tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/ol202649j
