((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile

Base Information

• Chemical Name: ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile
• CAS No.: 79857-75-3
• Molecular Formula: C₁₁H₁₆BrN
• Molecular Weight: 242.159
• Mol file: 79857-75-3.mol

Synonyms:((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile

Chemical Property of ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile

There total 2 articles about ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

geranyl cyanide (21677-96-3) → 2-(5-bromo-2,6,6-trimethylcyclohexen-1-yl)acetonitrile (57576-13-3) + ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile (79857-75-3) + ((1R,5S)-5-Bromo-2,6,6-trimethyl-cyclohex-2-enyl)-acetonitrile (57576-12-2,79857-74-2)

Guidance literature:

With bromodiethylsulfonium bromopentachloroantimonate; In nitromethane; at 25 ℃; for 0.0833333h; Inert atmosphere;

DOI:10.1002/anie.200903834

Reference yield:

(3E)-7-bromo-8-hydroxy-4,8-dimethyl-3-nonenenitrile (57576-16-6) → 2-(5-bromo-2,6,6-trimethylcyclohexen-1-yl)acetonitrile (57576-13-3) + ((1R,3S)-3-Bromo-2,2-dimethyl-6-methylene-cyclohexyl)-acetonitrile (79857-75-3) + ((1R,5S)-5-Bromo-2,6,6-trimethyl-cyclohex-2-enyl)-acetonitrile (57576-12-2,79857-74-2)

Guidance literature:

With boron trifluoride dimethanol; In dichloromethane; at 20 ℃; for 7h; Yield given. Yields of byproduct given;

DOI:10.1246/cl.1981.1125

upstream raw materials:

(3E)-7-bromo-8-hydroxy-4,8-dimethyl-3-nonenenitrile

geranyl cyanide