(4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate

Base Information

• Chemical Name: (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate
• CAS No.: 706782-27-6
• Molecular Formula: BF₄*C₄₈H₄₆ClP₄PdS
• Molecular Weight: 1007.53
• Mol file: 706782-27-6.mol

Synonyms:(4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate

Chemical Property of (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate

There total 1 articles about (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[Pd(tris-(2-(diphenylphosphino)ethyl)phosphine)](BF4)2 + p-Chlorothiophenol (106-54-7) → (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate (706782-27-6)

Guidance literature:

With NaOH; In water; acetonitrile; to soln. (Pd(pp3))(BF4)2 in MeCN 4-chlorothiophenol was added and soln. was neutralized with aq. NaOH; EtOH and water were added, ppt. was filtered and air-dried; elem. anal.;

DOI:10.1016/j.ica.2003.11.041

Reference yield: 76.0%

trans-bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate (706782-27-6) + water (7732-18-5) → trans-[Pt(4-chlorothiophenolato)2(PdCl(tris[2-(diphenylphosphino)ethyl]phosphine))2](BF4)2*H2O

Guidance literature:

In chloroform; room temp., Pt:Pd-compd. ratio was 1:2; elem. anal.;

DOI:10.1246/cl.2004.1286

Reference yield: 69.0%

diethyl ether (60-29-7,927820-24-4) + (4-chlorothiophenolato)(tris[2-(diphenylphosphino)ethyl]phosphine)chloropalladium(II) tetrafluoroborate (706782-27-6) + oxygen (80937-33-3) + p-Chlorothiophenol (106-54-7) → [Pd(4-Cltp)2(pp3O2)] (706782-33-4) + [Pd(4-Cltp)2(pp3O2)]*Et2O (706782-37-8)

Guidance literature:

With NaOH; In water; acetonitrile; Irradiation (UV/VIS); to soln. (Pd(4-ClTp)(pp3))(BF4) in MeCN 4-chlorothiophenol and aq. NaOH were added and stirred under luminescent lamp for several days; soln. was concd. to dryness, resdue was dissolved in CHCl3 and allowed to stand under Et2O vapor; elem. anal. - filtrate - (Pd(4-Cltp)2(p3O2))*OEt2;

DOI:10.1016/j.ica.2003.11.041

upstream raw materials:

p-Chlorothiophenol

Downstream raw materials:

[Pd(4-Cltp)(pp3O)](BF₄)*EtOH*H₂O

[Pd(4-Cltp)2(pp3O₂)]

[Pd(4-Cltp)2(pp3O₂)]*Et₂O