hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

Base Information

• Chemical Name: hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)
• CAS No.: 98715-91-4
• Molecular Formula: C₄₄H₂₁Cl₈FeN₄O
• Molecular Weight: 961.148
• Mol file: 98715-91-4.mol

Synonyms:hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

Chemical Property of hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

There total 10 articles about hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Fe(IV)=O(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphinate)](1+) → hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III) (98715-91-4)

Guidance literature:

With styrene; In water; acetonitrile; react. of complex with styrene in MeCN/H2O (1:1); further reagent: diphenylmethane; not isolated; detected by UV;

DOI:10.1016/j.inoche.2011.03.044

Reference yield:

iron 5,10,15,20-tetrakis-(2',6'-dichlorophenyl)porphyrinate (122752-63-0) → hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III) (98715-91-4)

Guidance literature:

With 2,4,6-Me₃Py; H₂O₂; In acetonitrile; byproducts: {2,4,6-Me3Py(OH)}(n);

DOI:10.1021/ja00216a020

Reference yield:

5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride (91042-27-2,186099-12-7) + water (7732-18-5) → hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III) (98715-91-4)

Guidance literature:

With basic alumina; In dichloromethane; 10 wt % H2O on alumina; evapn. (vac.);

DOI:10.1021/ja992373+

upstream raw materials:

5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride

iron(III)(meso-(tetrakis(2-6-dichlorophenyl)porphine))Br

water

iron 5,10,15,20-tetrakis-(2',6'-dichlorophenyl)porphyrinate

Downstream raw materials:

fluorenoneoximato(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

(m-chlorobenzoate)iron(III) 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

(tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)(OOCOC₆H₄m-Cl)

TPP(2,6-Cl)Fe(IV)=O(C₂H₅OH)