[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

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Chemical Name:[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium
CAS No.:223645-35-0
Molecular Formula:C₃₉H₃₇NSiTi
Molecular Weight:595.695
Hs Code.:

[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

Synonyms:[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

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Chemical Property of [1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

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Technology Process of [1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

There total 1 articles about [1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 233674-45-8
dichloro-[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]titanium

: 886-65-7,538-81-8
trans,trans-1,4-Diphenyl-1,3-butadiene

: 223645-35-0
[1-[(1,2,3,3a,11b-η)-1H-cyclopenta[l]-phenanthren-2-yl]-N-(1,1-dimethylethyl)-1,1-dimethylsilanaminato-(2-)-κ-N]-(1,4-diphenyl-1,3-butadiene-1,4-diyl)titanium

Guidance literature:: With C₄H₉Li; In toluene; under inert atm.; to warm soln. of Ti complex and ligand in toluene added soln. of n-BuLi; temp. climbed to 72°C; after 45 min mixt. refluxed for 1.5 h; cooled to about room temp.; volatiles removed (vac.); residue slurried in mixed hexanes at about 20°C for about 16 h; mixt. cooled to about -25°C for about 1 h; solid filtered (vac.); dried (vac.); extd. (hexane); after 6 h solid was ...;
DOI:10.1021/ja070061y