methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside

Base Information

• Chemical Name: methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside
• CAS No.: 79249-10-8
• Molecular Formula: C₁₆H₂₃NO₅
• Molecular Weight: 309.362
• Mol file: 79249-10-8.mol

Synonyms:methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside

Chemical Property of methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside

There total 10 articles about methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

acetic anhydride (108-24-7) + methyl 5-O-benzyl-3-deoxy-3-methylamino-β-D-xylofuranoside (79249-08-4) → methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside (79249-10-8)

Guidance literature:

In methanol; at 25 ℃;

DOI:10.1039/P19810002151

Reference yield:

methyl 3-acetamido-2,4-di-O-benzyl-3-deoxy-D-xylopyranoside (79248-95-6,79249-01-7) → methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside (79249-10-8)

Guidance literature:

Multi-step reaction with 4 steps

1: sodium hydride / dimethylformamide / 0.5 h / 25 °C

2: 46 percent / barium oxide, barium hydroxide octahydrate / 1 h

3: 14 percent / 0.1M-hydrochloric acid / dioxane / 2 h / 90 °C

4: 100 percent / methanol / 25 °C

With hydrogenchloride; barium hydroxide octahydrate; sodium hydride; barium(II) oxide; In 1,4-dioxane; methanol; N,N-dimethyl-formamide;

DOI:10.1039/P19810002151

Reference yield:

3-deoxy-1,2-O-isopropylidene-3-N-methylacetamido-α-D-xylofuranose (38711-54-5) → methyl 5-O-benzyl-3-deoxy-3-N-methylacetamido-β-D-xylofuranoside (79249-10-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 46 percent / barium oxide, barium hydroxide octahydrate / 1 h

2: 14 percent / 0.1M-hydrochloric acid / dioxane / 2 h / 90 °C

3: 100 percent / methanol / 25 °C

With hydrogenchloride; barium hydroxide octahydrate; barium(II) oxide; In 1,4-dioxane; methanol;

DOI:10.1039/P19810002151

upstream raw materials:

acetic anhydride

5-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-N-methylacetamido-α-D-xylofuranose

methyl 5-O-benzyl-3-deoxy-3-methylamino-β-D-xylofuranoside

3-deoxy-1,2-O-isopropylidene-3-N-methylacetamido-α-D-xylofuranose