5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane

Base Information

• Chemical Name: 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane
• CAS No.: 1268936-08-8
• Molecular Formula: C₂₁H₂₁BO₂
• Molecular Weight: 316.208
• Mol file: 1268936-08-8.mol

Synonyms:5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane

Chemical Property of 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane

There total 2 articles about 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

6-phenylnaphthalen-2-yl dimethylcarbamate (1268936-27-1) + 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane (201733-56-4) → 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane (1268936-08-8)

Guidance literature:

With bis(tricyclohexylphosphine)nickel(II) dichloride; sodium t-butanolate; tricyclohexylphosphine; In 1,2-dimethoxyethane; toluene; at 110 ℃; for 24h; Inert atmosphere;

DOI:10.1002/chem.201001943

Reference yield: 67.0%

2-fluoro-6-phenylnaphthalene (1214368-85-0) + 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane (201733-56-4) → 5,5-dimethyl-2-(6-phenylnaphthalen-2-yl)-1,3,2-dioxaborinane (1268936-08-8)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; sodium phenoxide; tricyclohexylphosphine; In tetrahydrofuran; at 110 ℃; for 15h; Schlenk technique; Inert atmosphere; Glovebox;

DOI:10.1021/jacs.5b08103

upstream raw materials:

6-phenylnaphthalen-2-yl dimethylcarbamate

2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane

2-fluoro-6-phenylnaphthalene