benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

Base Information

Chemical Name:benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester
CAS No.:929119-01-7
Molecular Formula:C₃₂H₄₅NO₅
Molecular Weight:523.713
Hs Code.:

benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1<i>H</i>-cyclopenta[<i>a</i>]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid <i>tert</i>-butyl ester

Synonyms:benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

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Chemical Property of benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

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Technology Process of benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

There total 3 articles about benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 929119-00-6
C₃₅H₅₁NO₆

: 929119-01-7
benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In benzene; for 2h;
DOI:10.1021/ja0684996

Reference yield:

: 929118-99-0
C₃₉H₅₅NO₈

: 929119-01-7
benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / Pd(PPh₃)4; morpholine / tetrahydrofuran / 0.5 h

2: DBU / benzene / 2 h

With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; benzene;
DOI:10.1021/ja0684996

Reference yield:

: C₃₉H₅₅NO₈

: 929119-01-7
benzyl-[6-(5-hydroxy-3-oxo-2,3,5,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalen-1-yl)-1-methyl-5-oxo-hexyl]-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: LiClO₄; LiOMe / diethyl ether / 3 h / 0 - 20 °C

2: 86 percent / Pd(PPh₃)4; morpholine / tetrahydrofuran / 0.5 h

3: DBU / benzene / 2 h

With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; lithium methanolate; lithium perchlorate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1021/ja0684996