4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

Base Information

Chemical Name:4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside
CAS No.:168567-06-4
Molecular Formula:C₂₂H₃₆I₂O₇Si
Molecular Weight:694.418
Hs Code.:

Synonyms:4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

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Chemical Property of 4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

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Technology Process of 4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

There total 4 articles about 4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 138785-35-0
4,6-diiodo-2,3-dimethoxy-5-methylphenyl 2-O-acetyl-6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

: 168567-06-4
4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

Guidance literature:: With sodium methylate; In methanol; for 4h; Ambient temperature;
DOI:10.1021/ja00126a013

Reference yield:

: 115592-76-2
5-hydroxy-2,6-diiodo-3,4-dimethoxytoluene

: 168567-06-4
4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / BF₃*Et₂O / CH₂Cl₂ / 0.5 h / -48 °C

2: 95 percent / MeONa / methanol / 4 h / Ambient temperature

With boron trifluoride diethyl etherate; sodium methylate; In methanol; dichloromethane;
DOI:10.1021/ja00126a013

Reference yield:

: 2-O-acetyl-6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-L-mannopyranosyl trichloracetimidate

: 168567-06-4
4,6-diiodo-2,3-dimethoxy-5-methylphenyl 6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / BF₃*Et₂O / CH₂Cl₂ / 0.5 h / -48 °C

2: 95 percent / MeONa / methanol / 4 h / Ambient temperature

With boron trifluoride diethyl etherate; sodium methylate; In methanol; dichloromethane;
DOI:10.1021/ja00126a013