C₂₇H₃₀Si

Base Information

• Chemical Name: C₂₇H₃₀Si
• CAS No.: 1352435-16-5
• Molecular Formula: C₂₇H₃₀Si
• Molecular Weight: 382.621
• Mol file: 1352435-16-5.mol

Synonyms:C₂₇H₃₀Si

Chemical Property of C₂₇H₃₀Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₃₀Si

There total 6 articles about C₂₇H₃₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C30H38Si2 (1352435-15-4) → C27H30Si (1352435-16-5)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; methanol;

DOI:10.1021/ja208444c

Reference yield:

tris-iso-propylsilyl acetylene (89343-06-6) → C27H30Si (1352435-16-5)

Guidance literature:

Multi-step reaction with 5 steps

1.1: copper; palladium; triethylamine / tetrahydrofuran

2.1: copper; palladium; triethylamine / tetrahydrofuran / Heating

3.1: potassium carbonate / tetrahydrofuran; methanol

4.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / tetrahydrofuran / Inert atmosphere

4.2: 48 h / Reflux; Inert atmosphere

5.1: potassium carbonate / tetrahydrofuran; methanol

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper; potassium carbonate; palladium; triethylamine; In tetrahydrofuran; methanol; 1.1: Sonogashira coupling / 2.1: Sonogashira coupling / 4.1: Sonogashira coupling / 4.2: Sonogashira coupling;

DOI:10.1021/ja208444c

Reference yield:

1-bromo-3-[(triisopropylsilyl)ethynyl]benzene → C27H30Si (1352435-16-5)

Guidance literature:

Multi-step reaction with 4 steps

1.1: copper; palladium; triethylamine / tetrahydrofuran / Heating

2.1: potassium carbonate / tetrahydrofuran; methanol

3.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / tetrahydrofuran / Inert atmosphere

3.2: 48 h / Reflux; Inert atmosphere

4.1: potassium carbonate / tetrahydrofuran; methanol

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper; potassium carbonate; palladium; triethylamine; In tetrahydrofuran; methanol; 1.1: Sonogashira coupling / 3.1: Sonogashira coupling / 3.2: Sonogashira coupling;

DOI:10.1021/ja208444c

upstream raw materials:

C₃₀H₃₈Si₂

1-Bromo-3-iodobenzene

tris-iso-propylsilyl acetylene

1-ethynyl-3-[2-(triisopropylsilyl)ethynyl]benzene

Downstream raw materials:

H-(C₂-1,3-C₆H₄)5-C₂H

C₆₀H₆₂Si₂