Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Base Information

Chemical Name:Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester
CAS No.:205584-90-3
Molecular Formula:C₂₃H₂₀O₅
Molecular Weight:376.409
Hs Code.:

Synonyms:Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Suppliers and Price of Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

There total 8 articles about Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 127661-25-0
(S)-benzyl 2-hydroxy-2-((S)-2-methyloxiran-2-yl)acetate

: 879-18-5
naphthalene-1-carbonic acid chloride

: 205584-90-3
Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 2h;

Reference yield:

: 541-47-9
3-Methylbutenoic acid

: 205584-90-3
Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 99 percent / n-Bu₄NBr, aq. KOH / CHCl₃ / 18 h / Heating

2: 80 percent / AD-mix-α, methanesulfonamide, NaHCO3 / H2O; 2-methyl-propan-2-ol / 60 h / 0 °C

3: 79 percent / Et₃N / CH₂Cl₂ / 3 h / 0 °C

4: 88 percent / Na₂CO₃ / acetonitrile / 48 h / Heating

5: 77 percent / (+/-)camphor-10-sulfonic acid / toluene / 4 h / Ambient temperature

6: vanadyl acetoacetonate, tert-butylhydroperoxide / CH₂Cl₂; decane / 18 h / 0 °C

7: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 2 h / 0 °C

With tert.-butylhydroperoxide; dmap; potassium hydroxide; AD-mix-α; bis(acetylacetonate)oxovanadium; methanesulfonamide; camphor-10-sulfonic acid; tetrabutylammomium bromide; sodium hydrogencarbonate; sodium carbonate; triethylamine; In decane; dichloromethane; chloroform; water; toluene; acetonitrile; tert-butyl alcohol;

Reference yield:

: 37526-89-9
benzyl 3-methylbut-2-enoate

: 205584-90-3
Naphthalene-1-carboxylic acid (S)-benzyloxycarbonyl-((S)-2-methyl-oxiranyl)-methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 80 percent / AD-mix-α, methanesulfonamide, NaHCO3 / H2O; 2-methyl-propan-2-ol / 60 h / 0 °C

2: 79 percent / Et₃N / CH₂Cl₂ / 3 h / 0 °C

3: 88 percent / Na₂CO₃ / acetonitrile / 48 h / Heating

4: 77 percent / (+/-)camphor-10-sulfonic acid / toluene / 4 h / Ambient temperature

5: vanadyl acetoacetonate, tert-butylhydroperoxide / CH₂Cl₂; decane / 18 h / 0 °C

6: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 2 h / 0 °C

With tert.-butylhydroperoxide; dmap; AD-mix-α; bis(acetylacetonate)oxovanadium; methanesulfonamide; camphor-10-sulfonic acid; sodium hydrogencarbonate; sodium carbonate; triethylamine; In decane; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol;