1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

Base Information

Chemical Name:1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate
CAS No.:1207893-58-0
Molecular Formula:BF₄*C₁₉H₂₃N₂
Molecular Weight:366.21
Hs Code.:

Synonyms:1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

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Chemical Property of 1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

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Technology Process of 1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

There total 1 articles about 1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 628-21-7
1,4-Diiodobutane

: 16596-01-3
N,N'-bis(2-methylphenyl)formamidine

: 1207893-58-0
1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

Guidance literature:: 1,4-Diiodobutane; N,N'-bis(2-methylphenyl)formamidine; With potassium carbonate; In acetonitrile; Reflux; Inert atmosphere;

With sodium tetrafluoroborate; In water; acetonitrile; at 20 ℃; for 0.166667h;
DOI:10.1002/ejic.200801179

Reference yield: 25.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 1207893-58-0
1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

: (CH₃C₆H₄)2C₅H₈N₂)(1,5-cyclooctadiene)rhodium(I)Cl

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; diethyl ether; (Ar), KN(SiMe3)2 and carbene precursor (1:1) dissolved in Et2O, stirred for 30 min, filtered into soln. of 0.5 equiv. of Rh complex in THF, stirred at room temp. for 1 h; evapd.(vac.), washed (hexane), dried (vac.), dissolved (CH2Cl2), pptd.(Et2O);
DOI:10.1002/ejic.200801179

Reference yield:

: 1152532-38-1,1152532-41-6
1,3-divinyl-1,1,3,3-tetramethyldisiloxane palladium⁽⁰⁾

: 1207893-58-0
1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate

: [Pd(1,3-bis(2-methylphenyl)-1,3-diazepan-2-ylidene)(dvtms)]

Guidance literature:: 1,3-bis(2-methylphenyl)-4,5,6,7-tetrahydro-3H-[1,3]diazepin-1-ium tetrafluoroborate; With potassium tert-butylate; In toluene; at 20 ℃; for 18h; Inert atmosphere; Schlenk technique;

1,3-divinyl-1,1,3,3-tetramethyldisiloxane palladium⁽⁰⁾; With tetramethyldivinyldisiloxane; In toluene; at 20 ℃; for 17h; Inert atmosphere; Schlenk technique;
DOI:10.1021/om300930w