methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate

Base Information

• Chemical Name: methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate
• CAS No.: 909103-60-2
• Molecular Formula: C₂₄H₂₉NO₈
• Molecular Weight: 459.496
• Mol file: 909103-60-2.mol

Synonyms:methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate

Chemical Property of methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate

There total 1 articles about methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-(2-propynyl)-D-glycero-D-galacto-non-2-enonate (909103-59-9) + iodobenzene (591-50-4) → methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate (909103-60-2)

Guidance literature:

With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In acetonitrile; at 20 ℃; for 6h;

DOI:10.1016/j.tet.2007.05.049

Reference yield: 82.0%

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate (909103-60-2) → methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate (909103-62-4)

Guidance literature:

With acetic acid; at 80 ℃; for 1h;

DOI:10.1016/j.tet.2007.05.049

upstream raw materials:

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-8,9-O-isopropylidene-4-O-(2-propynyl)-D-glycero-D-galacto-non-2-enonate

iodobenzene

Downstream raw materials:

methyl 5-acetamido-2,6-anhydro-3,5-dideoxy-4-O-[3-(phenyl)prop-2-ynyl]-D-glycero-D-galacto-non-2-enonate